Synonym
DYM10705; DYM 10705; DYM-10705; Cr(III) meso-Tetraphenylporphine Chloride (contains 1-3% chlorin);
InChi Key
DJXCXCGPVDGHEU-YKKPBKTHSA-M
InChi Code
InChI=1S/C44H28N4.ClH.Cr/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;
SMILES Code
Cl[Cr]1N2/C3=C(C4=CC=CC=C4)\C5=N/C(C=C5)=C(C6=CC=CC=C6)\C7=CC=C(N17)/C(C8=CC=CC=C8)=C(C=C9)\N=C9/C(C%10=CC=CC=C%10)=C2/C=C3
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
700.18
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Shahrokhian, S., Hamzehloei, A., Bagherzadeh, M.; Chromium(III) Porphyrin as a selective ionophore in a salicylate-selective membrane electrode. Anal Chem. 2002,14, 3312-3320. doi: 10.1021/ac020099n.
2.) Ganji, P., Doyle, D.J., Ibrahim, H.; In Situ Generation of the Coates Catalyst: A Practical and Versatile Catalytic System for the Carbonylation of meso-Epoxides. Lett. 2011, 12, 3142-3145. https://doi.org/10.1021/ol201043d
3.) Harrold, et al. Studies of Ring-Opening Reactions of Styrene Oxide by Chromium Tetraphenylporphyrin Initiators. Mechanistic and Stereochemical Considerations. Macromolecules 2013, 46, 3, 692–698. https://doi.org/10.1021/ma302492p
4.) Traylor, et al. Alkene epoxidations catalyzed by iron(III), manganese(III), and chromium(III) porphyrins. Effects of metal and porphyrin substituents on selectivity and regiochemistry of epoxidation. J. Am. Chem. Soc. 1989, 111, 19, 7443–7448. https://doi.org/10.1021/ja00201a026
5.) Miao, et al. Vanadium- and Chromium-Catalyzed Dehydrogenative Synthesis of Imines from Alcohols and Amines. Organometallics 2021, 40, 9, 1328–1335. https://doi.org/10.1021/acs.organomet.1c00123
6.) Balasanthiran, et al. Coupling of Propylene Oxide and Lactide at a Porphyrin Chromium(III) Center. J. Am. Chem. Soc. 2015, 137, 5, 1786–1789. https://doi.org/10.1021/ja512554t
