Synonym
Vanadyl octaethylporphine; Vanadyl octaethyl porphine;
InChi Key
XIJDRZKWTNMUAR-YAJYDHHFSA-N
InChi Code
InChI=1S/C36H44N4.O.V/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;;/h17-20H,9-16H2,1-8H3;;/q-2;;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;;
SMILES Code
O=[V]1N2/C3=C\C(C(CC)=C/4CC)=NC4=C/C5=C(C(CC)=C(/C=C6C(CC)=C(C(/C=C2/C(CC)=C3CC)=N/6)CC)N51)CC
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
599.72
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Kandrashkin, et al. Light-Induced Electron Spin Polarization in Vanadyl Octaethylporphyrin: I. Characterization of the Excited Quartet State. J. Phys. Chem. A 2006, 110, 31, 9607–9616. https://doi.org/10.1021/jp0620365
2.) Kandrashkin, et al. Light-Induced Electron Spin Polarization in Vanadyl Octaethylporphyrin: II. Dynamics of the Excited States. J. Phys. Chem. A 2006, 110, 31, 9617–9626. https://doi.org/10.1021/jp062037x
3.) Bonnett, et al. Chemistry of Vanadyl Porphyrins. Tetrahedron. Volume 34, Issue 3, 1978, Pages 379-385. https://doi.org/10.1016/S0040-4020(01)93596-3
4.) Miyake, et al. Scanning tunneling microscopy investigation of vanadyl and cobalt(II) octaethylporphyrin self-assembled monolayer arrays on graphite. Colloids and Surfaces A: Physicochemical and Engineering Aspects. Volumes 313–314, 1 February 2008, Pages 230-233. https://doi.org/10.1016/j.colsurfa.2007.05.073
5.) Chen, et al. Metal Porphyrin Adsorption onto Asphaltene in Pentane Solution: A Comparison between Vanadyl and Nickel Etioporphyrins. Energy Fuels 2017, 31, 4, 3592–3601.https://doi.org/10.1021/acs.energyfuels.6b03100
