Synonym
XXN22702; XXN-22702; XXN 22702; meso-Tetra(2,3-dimethoxyphenyl) porphine; 5,10,15,20-tetrakis(2,3-dimethoxyphenyl)porphyrin;
IUPAC/Chemical Name
5,10,15,20-tetrakis(2,3-dimethoxyphenyl)porphyrin
InChi Key
XQNRLSOCOYRFJL-XBWJNDOWSA-N
InChi Code
InChI=1S/C52H46N4O8/c1-57-41-17-9-13-29(49(41)61-5)45-33-21-23-35(53-33)46(30-14-10-18-42(58-2)50(30)62-6)37-25-27-39(55-37)48(32-16-12-20-44(60-4)52(32)64-8)40-28-26-38(56-40)47(36-24-22-34(45)54-36)31-15-11-19-43(59-3)51(31)63-7/h9-28,53,56H,1-8H3/b45-33-,45-34-,46-35-,46-37-,47-36-,47-38-,48-39-,48-40-
SMILES Code
COC1=C(OC)C=CC=C1/C(C(C=C/2)=NC2=C(C3=CC=C4N3)\C5=CC=CC(OC)=C5OC)=C6C=C/C(N\6)=C(C(C=C/7)=NC7=C4\C8=CC=CC(OC)=C8OC)\C9=CC=CC(OC)=C9OC
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
854.96
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Adineh, et al. Fabrication and analysis of dye-sensitized solar cells (DSSCs) using porphyrin dyes with catechol anchoring groups. RSC Advances, 2016, vol. 6, # 18, p. 14512 – 14521. https://doi.org/10.1039/C5RA23584G
2.) Osati, et al. Electrochemical synthesis of novel π-extended phenoxazine derivatives of porphyrincatecholes. Electrochimica Acta, 2011, vol. 56, # 25, p. 9426 – 9432. https://doi.org/10.1016/j.electacta.2011.08.030
3.) Aghabali, et al. Effects of methoxy-substituted metalloporphyrins in catalytic alkene epoxidation by n-Bu 4NHSO 5 . Journal of Porphyrins and Phthalocyanines, 2010, vol. 14, # 4, p. 335 – 342. https://doi.org/10.1142/S1088424610002136
4.) James, et al. Potency and selective toxicity of tetra(hydroxyphenyl)- and tetrakis(dihydroxyphenyl)porphyrins in human melanoma cells, with and without exposure to red light. Photochemistry and Photobiology, 1994, vol. 59, # 4, p. 441 – 447. https://doi.org/10.1111/j.1751-1097.1994.tb05062.x
