Synonym
meso-Octamethylcalix(4)pyrrole; meso Octamethylcalix(4)pyrrole; meso-Octamethylcalix (4)pyrrole;
IUPAC/Chemical Name
5,5,10,10,15,15,20,20-octamethyl-5H,10H,15H,20H,22H,24H-porphyrin
InChi Key
XZCHDFOYWDLFEY-UHFFFAOYSA-N
InChi Code
InChI=1S/C28H36N4/c1-25(2)17-9-11-19(29-17)26(3,4)21-13-15-23(31-21)28(7,8)24-16-14-22(32-24)27(5,6)20-12-10-18(25)30-20/h9-16,29-32H,1-8H3
SMILES Code
CC1(C2=CC=C(N2)C(C)(C3=CC=C(N3)C(C)(C4=CC=C(N4)C(C)(C5=CC=C1N5)C)C)C)C
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
428.62
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Gale, et al. Calix[4]pyrroles: Old Yet New Anion-Binding Agents. J. Am. Chem. Soc. 1996, 118, 21, 5140–5141. https://doi.org/10.1021/ja960307r
2.) Wintergerst, et al. Calix[4]pyrrole: A New Ion-Pair Receptor As Demonstrated by Liquid−Liquid Extraction. J. Am. Chem. Soc. 2008, 130, 12, 4129–4139. https://doi.org/10.1021/ja7102179
3.) Amharar, et al. Highly sensitive and cost-effective fluorescent turn-on sensors based on octamethylcalix[4]pyrrole receptor for the detection of fluoride anion. Dyes and Pigments. Volume 197, January 2022, 109918. https://doi.org/10.1016/j.dyepig.2021.109918
4.) Ruppert, et al. Calix[4]pyrrolato Stannate(II): A Tetraamido Tin(II) Dianion and Strong Metal-Centered σ-Donor. Angew. Chemie. Int.Ed. Volume 61, Issue 13, March 21, 2022. e202116615. https://doi.org/10.1002/anie.202116615
5.) Coskun, et al. Development of Highly Luminescent Water-Insoluble Carbon Dots by Using Calix[4]pyrrole as the Carbon Precursor and Their Potential Application in Organic Solar Cells. ACS Omega 2022, 7, 22, 18840–18851. https://doi.org/10.1021/acsomega.2c01795
6.) Ji, et al. Soft Materials Constructed Using Calix[4]pyrrole- and “Texas-Sized” Box-Based Anion Receptors. Acc. Chem. Res. 2019, 52, 7, 1915–1927. https://doi.org/10.1021/acs.accounts.9b00187
