Synonym
Ni(II) Octaethylporphine; Ni (II) Octaethylporphine;
InChi Key
DIGQQRGHPATISA-XTPDIVBZSA-N
InChi Code
InChI=1S/C36H44N4.Ni/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;/h17-20H,9-16H2,1-8H3;/q-2;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;
SMILES Code
CCC1=C(CC)/C2=C/C(C(CC)=C/3CC)=NC3=C/C4=C(CC)C(CC)=C5N4[Ni]N2/C1=C\C(C(CC)=C/6CC)=NC6=C/5
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
591.47
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Nandi, et al. Surface directed reversible imidazole ligation to nickel(ii) octaethylporphyrin at the solution/solid interface: a single molecule level study. Phys. Chem. Chem. Phys., 2016,18, 20819-20829. https://doi.org/10.1039/C6CP04454A
2.) Kruglik, et al. Time-resolved resonance Raman study of the primary photoprocesses of nickel(II) octaethylporphyrin in solution. Chemical Physics Letters. Volume 266, Issues 3–4, 28 February 1997, Pages 283-289.
3.) Balch, et al. Isolation and Crystallographic Characterization of Sm@C2v(3)-C80Through Cocrystal Formation with NiII(octaethylporphyrin) or Bis(ethylenedithio)tetrathiafulvalene. Inorg. Chem. 2013, 52, 3, 1275–1284. https://doi.org/10.1021/ic301794r
4.) Lexa, et al. Does one-electron transfer to nickel(II) porphyrins involve the metal or the porphyrin ligand? Inorg. Chem. 1989, 28, 1, 30–35. https://doi.org/10.1021/ic00300a009
5.) Bloodworth, et al. First Synthesis and Characterization of CH4@C60 Angew. Chemie. Int. ed. Volume 58, Issue 15, April 1, 2019, Pages 5038-5043. https://doi.org/10.1002/anie.201900983
6.) Li G, Graham A, Potter W, Grossman ZD, Oseroff A, Dougherty TJ, Pandey RK. A simple and efficient approach for the synthesis of fluorinated and nonfluorinated octaethylporphyrin-based benzochlorins with variable lipophilicity, their in vivo tumor uptake, and the preliminary in vitro photosensitizing efficacy. J Org Chem. 2001 Feb 23;66(4):1316-25. doi: 10.1021/jo001541+. PMID: 11312962
