Synonym
KWM39215; KWM-39215; KWM 39215; Fe(III) meso-Tetra (2,4,6 trimethylphenyl) Porphine Chloride; Fe (III) meso-Tetra (2,4,6 trimethylphenyl) Porphine Chloride;
InChi Key
KSUBTQBATWIZJZ-WSJWEZPUSA-M
InChi Code
InChI=1S/C56H52N4.ClH.Fe/c1-29-21-33(5)49(34(6)22-29)53-41-13-15-43(57-41)54(50-35(7)23-30(2)24-36(50)8)45-17-19-47(59-45)56(52-39(11)27-32(4)28-40(52)12)48-20-18-46(60-48)55(44-16-14-42(53)58-44)51-37(9)25-31(3)26-38(51)10;;/h13-28H,1-12H3;1H;/q-2;;+3/p-1/b53-41+,53-42+,54-43+,54-45+,55-44+,55-46+,56-47+,56-48+;;
SMILES Code
Cl[Fe](N1/C(C=C/C1=C(C2=C(C)C=C(C)C=C2C)/C3=N/C(C=C3)=C4/C5=C(C)C=C(C)C=C5C)=C6/C7=C(C)C=C(C)C=C7C)N8C4=CC=C8/C(C9=C(C)C=C(C)C=C9C)=C%10N=C6C=C\%10
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
872.36
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Groves, et al. High-valent iron-porphyrin complexes related to peroxidase and cytochrome P-450. J. Am. Chem. Soc. 1981, 103, 10, 2884–2886. https://doi.org/10.1021/ja00400a075
2.) Groves, et al. Epoxidation reactions catalyzed by iron porphyrins. Oxygen transfer from iodosylbenzene. J. Am. Chem. Soc. 1983, 105, 18, 5786–5791. https://doi.org/10.1021/ja00356a015
3.) Wolf, et al. Shape and stereoselective cyclopropanation of alkenes catalyzed by iron porphyrins. J. Am. Chem. Soc. 1995, 117, 36, 9194–9199. https://doi.org/10.1021/ja00141a011
4.) Melo, et al. Biomimetic oxidation of praziquantel catalysed by metalloporphyrins. Journal of Molecular Catalysis A: Chemical.Volume 226, Issue 1, 1 February 2005, Pages 23-31. https://doi.org/10.1016/j.molcata.2004.09.015
5.) Chen, et al. Ligand control in the photochemical generation of high-valent porphyrin-iron–oxo derivatives. Chem. Commun., 2015,51, 9949-9952. https://doi.org/10.1039/C5CC02852C
6.) Nishikawa, et al. Spectroscopic Evidence for Acid-Catalyzed Disproportionation Reaction of Oxoiron(IV) Porphyrin to Oxoiron(IV) Porphyrin π-Cation Radical and Iron(III) Porphyrin. J. Am. Chem. Soc. 2020, 142, 11, 4980–4984. https://doi.org/10.1021/jacs.9b13503
