Synonym
Cu(II) Octaethylporphine; Cu (II) Octaethylporphine;
InChi Key
WYWUPEFEFRBNGN-XTPDIVBZSA-N
InChi Code
InChI=1S/C36H44N4.Cu/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;/h17-20H,9-16H2,1-8H3;/q-2;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;
SMILES Code
CCC1=C(CC)C2=N/C1=C\C3=C(CC)C(CC)=C4N3[Cu]N5/C(C(CC)=C(CC)/C5=C/C6=N/C(C(CC)=C6CC)=C\4)=C\2
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
596.32
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Olmstead, et al. Interaction of Curved and Flat Molecular Surfaces. The Structures of Crystalline Compounds Composed of Fullerene (C60, C60O, C70, and C120O) and Metal Octaethylporphyrin Units. J. Am. Chem. Soc. 1999, 121, 30, 7090–7097. https://doi.org/10.1021/ja990618c
2.) Yoshimoto, et al. Two-Dimensional Supramolecular Organization of Copper Octaethylporphyrin and Cobalt Phthalocyanine on Au(111): Molecular Assembly Control at an Electrochemical Interface. J. Am. Chem. Soc. 2004, 126, 27, 8540–8545. https://doi.org/10.1021/ja0485210
3.) Roy, et al. Metal Ion Effects on Fullerene/Porphyrin Cocrystallization. Cryst. Growth Des. 2019, 19, 11, 6743–6751. https://doi.org/10.1021/acs.cgd.9b01092
4.) Minari, et al. Molecular-packing-enhanced charge transport in organic field-effect transistors based on semiconducting porphyrin crystals. Appl. Phys. Lett. 91, 123501 (2007); https://doi.org/10.1063/1.2786020
5.) Ramonio, et al. Layer-selective epitaxial self-assembly of porphyrins on ultrathin insulators. Chemical Physics Letters. Volume 417, Issues 1–3, 9 January 2006, Pages 22-27. https://doi.org/10.1016/j.cplett.2005.10.006
6.) Inamo, et al. Electron transfer reactions between copper(ii) porphyrin complexes and various oxidizing reagents in acetonitrile. Dalton Trans., 2004, 1703-1707. https://doi.org/10.1039/B403760J
