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MedKoo Cat#: 145631 | Name: Tritylamine

Description:

WARNING: This product is for research use only, not for human or veterinary use.

Tritylamine is an ammonia surrogate in the Ugi reaction.

Chemical Structure

Tritylamine
Tritylamine
CAS#5824-40-8

Theoretical Analysis

MedKoo Cat#: 145631

Name: Tritylamine

CAS#: 5824-40-8

Chemical Formula: C26H30O6

Exact Mass: 438.2000

Molecular Weight: 438.52

Elemental Analysis: C, 71.21; H, 6.90; O, 21.89

Price and Availability

This product is currently not in stock but may be available through custom synthesis. To ensure cost efficiency, the minimum order quantity is 1 gram. The estimated lead time is 2 to 4 months, with pricing dependent on the complexity of the synthesis (typically high for intricate chemistries). Quotes for quantities below 1 gram will not be provided. To request a quote, please click the button below. Note: If this product becomes available in stock in the future, pricing will be listed accordingly.
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Related CAS #
No Data
Synonym
Tritylamine; NSC-1154; Triphenylmethylamine;
IUPAC/Chemical Name
(R,E)-1-(2,4-dihydroxy-6-methoxy-3-(5-methyl-2-(prop-1-en-2-yl)hex-4-en-1-yl)phenyl)-3-(2,4-dihydroxyphenyl)prop-2-en-1-one
InChi Key
BZVJOYBTLHNRDW-UHFFFAOYSA-N
InChi Code
1S/C19H17N/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H,20H2
SMILES Code
NC(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 438.52 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1: Bhela IP, Serafini M, Del Grosso E, Tron GC, Pirali T. Tritylamine as an Ammonia Surrogate in the Ugi Reaction Provides Access to Unprecedented 5-Sulfamido Oxazoles Using Burgess-type Reagents. Org Lett. 2021 May 7;23(9):3610-3614. doi: 10.1021/acs.orglett.1c01002. Epub 2021 Apr 29. PMID: 33913716; PMCID: PMC8289289. 2: Zhao T, Boltjes A, Herdtweck E, Dömling A. Tritylamine as an ammonia surrogate in the Ugi tetrazole synthesis. Org Lett. 2013 Feb 1;15(3):639-41. doi: 10.1021/ol303348m. Epub 2013 Jan 18. PMID: 23331054. 3: Ami T, Oka K, Tsuchiya K, Tohnai N. Porous Organic Salts: Diversifying Void Structures and Environments. Angew Chem Int Ed Engl. 2022 Aug 1;61(31):e202202597. doi: 10.1002/anie.202202597. Epub 2022 May 19. PMID: 35502601. 4: Hoffman RV, Tao J. A Stereocontrolled Synthesis of Monofluoro Ketomethylene Dipeptide Isosteres. J Org Chem. 1999 Jan 8;64(1):126-132. doi: 10.1021/jo981334y. PMID: 11674093. 5: Gao W, Liu Z, Dai X, Sun W, Gong Q, Li J, Ge Y. Color-Tunable Ultralong Organic Phosphorescence: Commercially Available Triphenylmethylamine for UV- Light Response and Anticounterfeiting. Chem Asian J. 2023 Aug 15;18(16):e202300450. doi: 10.1002/asia.202300450. Epub 2023 Jul 7. PMID: 37387329. 6: Okubo K, Oka K, Tsuchiya K, Tomimoto A, Tohnai N. Spirobifluorene-Based Porous Organic Salts: Their Porous Network Diversification and Construction of Chiral Helical Luminescent Structures. Angew Chem Int Ed Engl. 2024 Apr 8;63(15):e202400475. doi: 10.1002/anie.202400475. Epub 2024 Feb 16. PMID: 38279903. 7: Chen S, Coward JK. Investigations on New Strategies for the Facile Synthesis of Polyfunctionalized Phosphinates: Phosphinopeptide Analogues of Glutathionylspermidine. J Org Chem. 1998 Feb 6;63(3):502-509. doi: 10.1021/jo971318l. PMID: 11672038. 8: Zheng Y, Chen P, Niu Z, Wang E. Excimer emission from polycyclic arenes bearing triphenylmethyl group: Solid-state fluorescence, mechanofluorochromism, aggregation-induced emission and cell imaging application. Spectrochim Acta A Mol Biomol Spectrosc. 2024 May 5;312:124035. doi: 10.1016/j.saa.2024.124035. Epub 2024 Feb 12. PMID: 38422929. 9: Khrustalev VN, Borisova IV, Zemlyansky NN, Antipin MY. A new polymorph of triphenylmethylamine: the effect of hydrogen bonding. Acta Crystallogr C. 2009 Feb;65(Pt 2):o31-4. doi: 10.1107/S0108270108042911. Epub 2009 Jan 10. PMID: 19190382. 10: Hasegawa T, Ohkubo K, Hisaki I, Miyata M, Tohnai N, Fukuzumi S. Photoinduced electron transfer in porous organic salt crystals impregnated with fullerenes. Chem Commun (Camb). 2016 Jun 28;52(51):7928-31. doi: 10.1039/c6cc02377k. Epub 2016 May 16. PMID: 27182038. 11: Tohnai N, Mizobe Y, Doi M, Sukata S, Hinoue T, Yuge T, Hisaki I, Matsukawa Y, Miyata M. Well-designed supramolecular clusters comprising triphenylmethylamine and various sulfonic acids. Angew Chem Int Ed Engl. 2007;46(13):2220-3. doi: 10.1002/anie.200603841. PMID: 17295373. 12: Ami T, Oka K, Kitajima S, Tohnai N. Highly Fluorinated Nanospace in Porous Organic Salts with High Water Stability/Capability and Proton Conductivity. Angew Chem Int Ed Engl. 2024 Sep 9;63(37):e202407484. doi: 10.1002/anie.202407484. Epub 2024 Aug 4. PMID: 38899387. 13: Priego EM, Balzarini J, Karlsson A, Camarasa MJ, Pérez-Pérez MJ. Synthesis and evaluation of thymine-derived carboxamides against mitochondrial thymidine kinase (TK-2) and related enzymes. Bioorg Med Chem. 2004 Oct 1;12(19):5079-90. doi: 10.1016/j.bmc.2004.07.036. PMID: 15351391. 14: Yamamoto A, Hasegawa T, Hamada T, Hirukawa T, Hisaki I, Miyata M, Tohnai N. Role-allocated combination of two types of hydrogen bonds towards constructing a breathing diamondoid porous organic salt. Chemistry. 2013 Feb 25;19(9):3006-16. doi: 10.1002/chem.201202959. Epub 2013 Jan 10. PMID: 23307443.