Synonym
NDL88456; NDL 88456; NDL-88456; Pt(II) meso-Tetra (4-carboxyphenyl) porphine; Pt (II) meso-Tetra (4-carboxyphenyl) porphine; Pt(II) meso-Tetra (4-carboxyphenyl) porphyrin;
InChi Key
NRXFLRJMHNYICF-DAJBKUBHSA-L
InChi Code
InChI=1S/C48H30N4O8.Pt/c53-45(54)29-9-1-25(2-10-29)41-33-17-19-35(49-33)42(26-3-11-30(12-4-26)46(55)56)37-21-23-39(51-37)44(28-7-15-32(16-8-28)48(59)60)40-24-22-38(52-40)43(36-20-18-34(41)50-36)27-5-13-31(14-6-27)47(57)58;/h1-24H,(H6,49,50,51,52,53,54,55,56,57,58,59,60);/q;+2/p-2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;
SMILES Code
O=C(O)C1=CC=C(C=C1)/C2=C3N4/C(C=C/3)=C(C5=CC=C(C=C5)C(O)=O)\C(C=C/6)=NC6=C(C7=CC=C(C=C7)C(O)=O)/C8=CC=C(N8[Pt]4)/C(C9=CC=C(C=C9)C(O)=O)=C%10N=C2C=C\%10
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
983.86
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Vanderkooi, Jane M., Maniara, Grzegorz, Green, Thomas J., Wilson, David F., An optical method for measurement of dioxygen concentration based upon quenching of phosphorescence, Journal of Biological Chemistry (1987), 262(12), 5476-82.
2.) Yang, et al. Real-Time Monitoring of Dissolved Oxygen with Inherent Oxygen-Sensitive Centers in Metal–Organic Frameworks. Chem. Mater. 2016, 28, 8, 2652–2658
3.) Hill, et al. Photon Upconversion and Photocurrent Generation via Self-Assembly at Organic–Inorganic Interfaces. J. Phys. Chem. Lett. 2015, 6, 22, 4510–4517.
4.) Hu, et al. Incorporating porphyrin-Pt in light-harvesting metal-organic frameworks for enhanced visible light-driven hydrogen production. Chinese Journal of Catalysis. Volume 42, Issue 8, August 2021, Pages 1345-1351
5.) Zhu, et al. Dual-Emissive Platinum(II) Metallacage with a Sensitive Oxygen Response for Imaging of Hypoxia and Imaging-Guided Chemotherapy. Angew. Chemie. Int. Ed. Volume 59, Issue 45, November 2, 2020, Pages 20208-20214. https://doi.org/10.1002/anie.202009442
