Synonym
BKN95118; BKN-95118; BKN 95118; Pd(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin; Pd (II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin;
InChi Key
BVVWQTKDQGGJJS-KCVIGMLFSA-N
InChi Code
InChI=1S/C60H32F4N4.Pd/c61-37-25-17-33(18-26-37)49-53-41-9-1-2-10-42(41)54(65-53)50(34-19-27-38(62)28-20-34)56-45-13-5-6-14-46(45)58(67-56)52(36-23-31-40(64)32-24-36)60-48-16-8-7-15-47(48)59(68-60)51(35-21-29-39(63)30-22-35)57-44-12-4-3-11-43(44)55(49)66-57;/h1-32H;/q-2;+2/b53-49-,54-50-,55-49-,56-50-,57-51-,58-52-,59-51-,60-52-;
SMILES Code
FC1=CC=C(C=C1)/C(C(C2=C/3C=CC=C2)=NC3=C4\C5=CC=C(C=C5)F)=C(C6=C(/C7=C8\C9=CC=C(C=C9)F)C=CC=C6)/N7[Pd]N%10C4=C%11C(C=CC=C%11)=C%10/C(C%12=CC=C(C=C%12)F)=C%13N=C8C%14=C\%13C=CC=C%14
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
991.36
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Niedermair, et al. Tunable Phosphorescent NIR Oxygen Indicators Based on Mixed Benzo- and Naphthoporphyrin Complexes. Inorg. Chem. 2010, 49, 20, 9333–9342. https://doi.org/10.1021/ic100955z
2.) Borisov, et al. New NIR-emitting complexes of platinum(II) and palladium(II) with fluorinated benzoporphyrins. Journal of Photochemistry and Photobiology A: Chemistry. Volume 201, Issues 2–3, 25 January 2009, Pages 128-135. https://doi.org/10.1016/j.jphotochem.2008.10.003
3.) Ehgartner, et al. Online analysis of oxygen inside silicon-glass microreactors with integrated optical sensors. Sensors and Actuators B: Chemical. Volume 228, 2 June 2016, Pages 748-757. https://doi.org/10.1016/j.snb.2016.01.050
4.) Monguzzi, et al. Efficient Broadband Triplet–Triplet Annihilation-Assisted Photon Upconversion at Subsolar Irradiance in Fully Organic Systems. Advanced Functional Materials. Volume 25, Issue 35, September 16, 2015, Pages 5617-5624. https://doi.org/10.1002/adfm.201502507
5.) Kwak, et al. Deactivation of redox mediators in lithium-oxygen batteries by singlet oxygen. Nat Commun 10, 1380 (2019). https://doi.org/10.1038/s41467-019-09399-0
