Synonym
LGN14682; LGN 14682; LGN-14682; Ni(II) meso-Tetra (4-pyridyl) porphine;
InChi Key
LNHHCWBXIHHQIW-GFPSKMGBSA-N
InChi Code
InChI=1S/C40H24N8.Ni/c1-2-30-38(26-11-19-42-20-12-26)32-5-6-34(47-32)40(28-15-23-44-24-16-28)36-8-7-35(48-36)39(27-13-21-43-22-14-27)33-4-3-31(46-33)37(29(1)45-30)25-9-17-41-18-10-25;/h1-24H;/q-2;+2/b37-29-,37-31-,38-30-,38-32-,39-33-,39-35-,40-34-,40-36-;
SMILES Code
C1(/C2=C3N=C(C=C/3)/C(C4=CC=NC=C4)=C(C=C/C5=C6\C7=CC=NC=C7)\N5[Ni]N8C2=CC=C8/C(C9=CC=NC=C9)=C%10N=C6C=C\%10)=CC=NC=C1
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
675.38
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Kadish, et al. Electrochemical and spectroelectrochemical studies of nickel(II) porphyrins in dimethylformamide. Inorganic Chemistry, 1988, vol. 27, # 7, p. 1198 – 1204. https://doi.org/10.1021/ic00280a021
2.) Li, et al. Interpenetrated Metal-Porphyrinic Framework for Enhanced Nonlinear Optical Limiting. Journal of the American Chemical Society, 2021, vol. 143, # 41, p. 17162 – 17169. https://doi.org/10.1021/jacs.1c07803
3.) Barbosa, et al. Nonlinear absorption dynamics in tetrapyridyl metalloporphyrins. Journal of Physical Chemistry B, 2005, vol. 109, # 36, p. 17340 – 17345. https://doi.org/10.1021/jp052168i
4.) Garcia, et al. Synthesis, spectral, electrochemical and flash photolysis studies of Fe(II), Ni(II) tetrapyridylporphyrins coordinated at the periphery with chromium(III) phenanthroline complexes. Inorganica Chimica Acta, 2012, vol. 386, p. 73 – 82. https://doi.org/10.1016/j.ica.2012.02.023
5.) Tomita, et al. Control of supramolecular organizations by coordination bonding in tetrapyridylporphyrin thin films. Chemical Communications, 2022, vol. 58, # 13, p. 2116 – 2119. https://doi.org/10.1039/D1CC06169K
