Synonym
meso-Tetra(4-pyridyl)porphine; 5,10,15,20-tetra(pyridin-4-yl)porphyrin;
IUPAC/Chemical Name
5,10,15,20-tetra(pyridin-4-yl)porphyrin
InChi Key
DNZSHSJERXNJGX-XXDGMDECSA-N
InChi Code
InChI=1S/C40H26N8/c1-2-30-38(26-11-19-42-20-12-26)32-5-6-34(47-32)40(28-15-23-44-24-16-28)36-8-7-35(48-36)39(27-13-21-43-22-14-27)33-4-3-31(46-33)37(29(1)45-30)25-9-17-41-18-10-25/h1-24,45,48H/b37-29-,37-31-,38-30-,38-32-,39-33-,39-35-,40-34-,40-36-
SMILES Code
C1(/C2=C3N/C(C=C/3)=C(C4=CC=NC=C4)\C5=N/C(C=C5)=C(C6=CC=NC=C6)\C(N7)=CC=C7/C(C8=CC=NC=C8)=C9N=C2C=C\9)=CC=NC=C1
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
618.70
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Akins DL, Zhu H-R, Guo C. 1996. Aggregation of Tetraaryl-Substituted Porphyrins in Homogeneous Solution. Phys. Chem. 100:5420-5
2.) Anderson S, Anderson HL, Bashall A, McPartlin M, Sanders JKM. 1995. Assembly and crystal structure of a photoactive array of five porphyrins. Chem., Int. Ed. Engl. 34:1096-9
3.) Auwarter W, Weber-Bargioni A, Brink S, Riemann A, Schiffrin A, et al. 2007. Controlled metalation of self-assembled porphyrin nanoarrays in two dimensions. ChemPhysChem 8:250-
4.) Bernadou J, Pratviel G, Bennis F, Girardet M, Meunier B. 1989. Potassium monopersulfate and a water-soluble manganese porphyrin complex, [Mn(TMPyP)](OAc)5, as an efficient reagent for the oxidative cleavage of DNA. Biochemistry 28:7268-75
4.)Caughey WS, Raymond LD, Horiuchi M, Caughey B. 1998. Inhibition of protease-resistant prion protein formation by porphyrins and phthalocyanines. Natl. Acad. Sci. U. S. A. 95:12117-22
6.) Drain CM, Nifiatis F, Vasenko A, Batteas JD. 1998. Porphyrin tessellation by design: metal-mediated self-assembly of large arrays and tapes. Chem., Int. Ed. 37:2344-7
7.) Fleischer EB, Shachter AM. 1991. Coordination oligomers and a coordination polymer of zinc tetraarylporphyrins. Chem. 30:3763-9
8.)Gong X, Milic T, Xu C, Batteas JD, Drain CM. 2002. Preparation and Characterization of Porphyrin Nanoparticles. Am. Chem. Soc. 124:14290-1
9.)Hagrman D, Hagrman PJ, Zubieta J. 1999. Solid-state coordination chemistry: the self-assembly of microporous organic-inorganic hybrid frameworks constructed from tetrapyridylporphyrin and bimetallic oxide chains or oxide clusters. Chem., Int. Ed. 38:3165-8
10.) Ishii H, Seki K. 1997. Energy level alignment at organic/metal interfaces studied by UV photoemission: breakdown of traditional assumption of a common vacuum level at the interface. IEEE Trans. Electron Devices 44:1295-301
 Protoporphyrin IX chloride2032.jpg "Mn(III) Protoporphyrin IX chloride")
