Synonym
Ir(III) Octaethylporphine chloride; Ir (III) Octaethylporphine chloride;
InChi Key
OMADUDCQGOHOHI-SBYLDBAISA-M
InChi Code
InChI=1S/C36H44N4.CO.ClH.Ir/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;1-2;;/h17-20H,9-16H2,1-8H3;;1H;/q-2;;;+3/p-1/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;;;
SMILES Code
CCC1=C(CC)C2=N/C1=C\C3=C(CC)C(CC)=C4N3[Ir](Cl)(N5/C(C(CC)=C(CC)/C5=C/C6=N/C(C(CC)=C6CC)=C\4)=C\2)C#O
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
788.45
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Lopez-Sanchez, et al. Efficient Intramolecular C–H Insertion Catalyzed by Iridium Porphyrin Complexes. Synlett 2012; 23(17): 2469-2472. 10.1055/s-0032-1317296
2.) Bian, et al. Base-Promoted C–O Bond Cleavage of Primary Alcohols by Iridium(III) Porphyrin Chloride. Organometallics 2020, 39, 8, 1376–1383. https://doi.org/10.1021/acs.organomet.0c00100
3.) Koren, et al. Strongly Phosphorescent Iridium(III)–Porphyrins – New Oxygen Indicators with Tuneable Photophysical Properties and Functionalities. EurJIC, Volume 2011, Issue 10, April 2011, Pages 1531-1534. https://doi.org/10.1002/ejic.201100089
4.) Huckaba, et al. Strategies for Tuning Emission Energy in Phosphorescent Ir(III) Complexes. Comments on Inorganic Chemistry, 37:3, 117-145, 2017. 10.1080/02603594.2016.1207064
5.) Koren, et al. Complexes of IrIII-Octaethylporphyrin with Peptides as Probes for Sensing Cellular O2. ChemBioChem, Volume 13, Issue 8, May 29, 2012, Pages 1184-1190. https://doi.org/10.1002/cbic.201200083
