Synonym
CYM33520; CYM-33520; CYM 33520; Ga (III) meso-Tetraphenylporphine chloride; Ga(III) meso-Tetraphenylporphine chloride;
InChi Key
CYNJWPJXZCABKS-YKKPBKTHSA-M
InChi Code
InChI=1S/C44H28N4.ClH.Ga/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;
SMILES Code
Cl[Ga]1N2/C3=C(C(C=C/4)=NC4=C(C5=CC=C(N51)/C(C6=CC=CC=C6)=C7C=CC(/C(C8=CC=CC=C8)=C2/C=C3)=N/7)\C9=CC=CC=C9)/C%10=CC=CC=C%10
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
717.91
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Wang, et al. Electrocatalytic hydrogen evolution with gallium hydride and ligand-centered reduction. Chem. Sci., 2019,10, 2308-2314. https://doi.org/10.1039/C8SC05247F
2.) Choi, et al. In Vitro Efficacy of Free and Nanoparticle Formulations of Gallium(III) meso-Tetraphenylporphyrine against Mycobacterium avium and Mycobacterium abscessus and Gallium Biodistribution in Mice. Mol. Pharmaceutics 2018, 15, 3, 1215–1225. https://doi.org/10.1021/acs.molpharmaceut.7b01036
3.) DiPasquale, et al. Hydrogen Peroxide: A Poor Ligand to Gallium Tetraphenylporphyrin. J. Am. Chem. Soc. 2008, 130, 6, 1812–1813. https://doi.org/10.1021/ja077598w
4.) Meininger, et al. Gallium(III) Tetraphenylporphyrinates Containing Hydrosulfide and Thiolate Ligands: Structural Models for Sulfur-Bound Iron(III) Hemes. Inorg. Chem. 2016, 55, 5, 2421–2426. https://doi.org/10.1021/acs.inorgchem.5b02822
5.) Ebeid, et al. Spectroscopic and stability characteristics of Ga-tetraphenyl porphyrin- and Ge- and Sn-tetra (p-methyl-phenyl) porphyrin chlorides. Spectrochimica Acta Part A: Molecular Spectroscopy. Volume 44, Issue 2, 1988, Pages 127-130. https://doi.org/10.1016/0584-8539(88)80235-6
6.) Ohno, et al. Luminescence of some metalloporphins including the complexes of the IIIb metal group. J. Chem. Phys. 82, 1779 (1985); https://doi.org/10.1063/1.448410
