Synonym
RVM65716; RVM-65716; RVM 65716; Fe(III) meso-Tetra(Pentafluorophenyl) Porphine Chloride; Fe (III) meso-Tetra(Pentafluorophenyl) Porphine Chloride;
InChi Key
RVNJZXLLVARDGN-VTVSBRCESA-M
InChi Code
InChI=1S/C44H8F20N4.ClH.Fe/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;;/h1-8H;1H;/q-2;;+3/p-1/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;;
SMILES Code
FC(C(F)=C(F)C(F)=C1F)=C1/C2=C3C=C/C4=C(C5=C(F)C(F)=C(F)C(F)=C5F)/C(C=C/6)=NC6=C(C7=C(F)C(F)=C(F)C(F)=C7F)/C8=CC=C(/C(C9=C(F)C(F)=C(F)C(F)=C9F)=C%10C=CC2=N/%10)N8[Fe](Cl)N4\3
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
1,063.84
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Balogh-Weiser, et al. Magnetic Nanoparticles with Dual Surface Functions—Efficient Carriers for Metalloporphyrin-Catalyzed Drug Metabolite Synthesis in Batch and Continuous-Flow Reactors. Nanomaterials 2020, 10, 2329. https://doi.org/10.3390/nano10122329
2.) Engbers, et al. Toward Environmentally Benign Electrophilic Chlorinations: From Chloroperoxidase to Bioinspired Isoporphyrins, Inorg. Chem. 2022, 61, 21, 8105–8111. https://doi.org/10.1021/acs.inorgchem.2c00602
3.) Hiroshi, et al. Characterization of High Valent Iron Porphyrin in Catalytic Reaction by Iron(III) Tetrapentafluorophenylporphyrin. Chemistry Letters, 1994, Vol.23, No.8, 1491-1494. https://www.journal.csj.jp/doi/abs/10.1246/cl.1994.1491
4.) Franke, et al. Axial Ligand and Spin-State Influence on the Formation and Reactivity of Hydroperoxo–Iron(III) Porphyrin Complexes. Chemistry, a European Journal.Volume 18, Issue 22, May 29, 2012, Pages 6935-6949. https://doi.org/10.1002/chem.201103036
5.) Pereira, et al. Metalloporphyrins: Bioinspired Oxidation Catalysts. ACS Catal. 2018, 8, 11, 10784–10808. https://doi.org/10.1021/acscatal.8b01871
