MedKoo Cat#: 161112 | Name: LAN85211
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Description:

WARNING: This product is for research use only, not for human or veterinary use.

LAN85211, also known as Cu(II) meso-Tetra(o-dichlorophenyl) porphine, is a synthetic porphyrin. LAN85211 is used as a catalyst in click chemistry, specifically towards triazoles in water. This product has no formal name at the moment. For the convenience of communication, a temporal code name was therefore proposed according to MedKoo Chemical Nomenclature (see web page: https://www.medkoo.com/page/naming)

Chemical Structure

LAN85211
LAN85211
CAS#135685-21-1

Theoretical Analysis

MedKoo Cat#: 161112

Name: LAN85211

CAS#: 135685-21-1

Chemical Formula: C44H20Cl8CuN4

Exact Mass: 946.8492

Molecular Weight: 951.82

Elemental Analysis: C, 55.52; H, 2.12; Cl, 29.80; Cu, 6.68; N, 5.89

Price and Availability

Size Price Availability Quantity
100mg USD 845.00 2 Weeks
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Related CAS #
No Data
Synonym
LAN85211; LAN 85211; LAN-85211; Cu(II) meso-Tetra(o-dichlorophenyl) porphine;
IUPAC/Chemical Name
n/a
InChi Key
LQUSZTUXVUNEGU-AQZHRKEBSA-N
InChi Code
InChI=1S/C44H20Cl8N4.Cu/c45-21-5-1-6-22(46)37(21)41-29-13-15-31(53-29)42(38-23(47)7-2-8-24(38)48)33-17-19-35(55-33)44(40-27(51)11-4-12-28(40)52)36-20-18-34(56-36)43(32-16-14-30(41)54-32)39-25(49)9-3-10-26(39)50;/h1-20H;/q-2;+2/b41-29+,41-30+,42-31+,42-33+,43-32+,43-34+,44-35+,44-36+;
SMILES Code
ClC1=CC=CC(Cl)=C1/C2=C(C=C/3)/N([Cu]N4C(/C(C5=C(Cl)C=CC=C5Cl)=C6C=CC7=N/6)=CC=C4/C(C8=C(Cl)C=CC=C8Cl)=C9C=CC2=N/9)C3=C7\C%10=C(Cl)C=CC=C%10Cl
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 951.82 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1.) Sharghi, et al. Immobilization of Porphyrinatocopper Nanoparticles onto Activated Multi-Walled Carbon Nanotubes and a Study of its Catalytic Activity as an Efficient Heterogeneous Catalyst for a Click Approach to the Three-Component Synthesis of 1,2,3-Triazoles in Water. Advanced Synthesis and Catalysis. Volume 351, Issue 14-15, October 2009, Pages 2391-2410. https://doi.org/10.1002/adsc.200900353 2.) Ehlinger, et al. Structure and Apparent Reactivity of the π-Cation Radical Derivatives of Zinc and Copper 5,10,15,20-Tetra(2,6-dichlorophenyl)porphyrinate. Inorg. Chem. 1999, 38, 6, 1316–1321. https://doi.org/10.1021/ic981041n 3.) Cunningham, et al. EPR Spectra, Luminescence Data, and Radiationless Decay Processes of Copper(II) Porphyrins. Inorg. Chem. 1997, 36, 4, 608–613. https://doi.org/10.1021/ic960604x 4.) Li, Y. Solvent effects on photophysical properties of copper and zinc porphyrins. Chin. Sci. Bull. 53, 3615–3619 (2008). https://doi.org/10.1007/s11434-008-0498-8