Synonym
Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine
InChi Key
AFWJXYNTLVOWIW-XYIYAAJRSA-N
InChi Code
InChI=1S/C56H52N4.Co/c1-29-21-33(5)49(34(6)22-29)53-41-13-15-43(57-41)54(50-35(7)23-30(2)24-36(50)8)45-17-19-47(59-45)56(52-39(11)27-32(4)28-40(52)12)48-20-18-46(60-48)55(44-16-14-42(53)58-44)51-37(9)25-31(3)26-38(51)10;/h13-28H,1-12H3;/q-2;+2/b53-41+,53-42+,54-43+,54-45+,55-44+,55-46+,56-47+,56-48+;
SMILES Code
CC(C=C1C)=CC(C)=C1/C(C2=CC=C3N2[Co]N4/C(C=C/C4=C(C5=N/C(C=C5)=C3/C6=C(C)C=C(C)C=C6C)\C7=C(C)C=C(C)C=C7C)=C8/C9=C(C)C=C(C)C=C9C)=C%10N=C8C=C/%10
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
840.00
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Kuijpers, et al. Cobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C−H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles. Chemistry, a European Journal. Volume 23, Issue 33, June 12, 2017, Pages 7945-7952. https://doi.org/10.1002/chem.201700358
2.) Harden, et al. Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source. Chem. Commun., 2007, 4644-4646.https://doi.org/10.1039/B710677G
3.) Li, et al. Exchange of Organic Radicals with Organo-Cobalt Complexes Formed in the Living Radical Polymerization of Vinyl Acetate. J. Am. Chem. Soc. 2008, 130, 40, 13373–13381. https://doi.org/10.1021/ja804010h
4.) Zhao, et al. Visible Light Induced Living/Controlled Radical Polymerization of Acrylates Catalyzed by Cobalt Porphyrins. Macromolecules 2014, 47, 18, 6238–6245. https://doi.org/10.1021/ma5014385
5.) Peng, et al. Formation and Interconversion of Organo-Cobalt Complexes in Reactions of Cobalt(II) Porphyrins with Cyanoalkyl Radicals and Vinyl Olefins. Inorg. Chem. 2009, 48, 11, 5039–5046. https://doi.org/10.1021/ic900384n
6.) Chan, et al. Electronic Effects of Ligands on the Cobalt(II)–Porphyrin-Catalyzed Direct C–H Arylation of Benzene. EurJIC. Volume 2012, Issue3, January 2012, Pages 485-489. https://doi.org/10.1002/ejic.201100780
