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MedKoo Cat#: 574180 | Name: Spinosyn A aglycone
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Description:

WARNING: This product is for research use only, not for human or veterinary use.

Spinosyn A aglycone is an aglycone form of the insecticide spinosyn A. It is formed by acid hydrolysis of spinosyn A 17-pseudoaglycone and has no insecticidal activity at concentrations up to 64 ppm.

Chemical Structure

Spinosyn A aglycone
Spinosyn A aglycone
CAS#149560-97-4

Theoretical Analysis

MedKoo Cat#: 574180

Name: Spinosyn A aglycone

CAS#: 149560-97-4

Chemical Formula: C24H34O5

Exact Mass: 402.2406

Molecular Weight: 402.53

Elemental Analysis: C, 71.61; H, 8.51; O, 19.87

Price and Availability

Size Price Availability Quantity
1mg USD 650.00 2 weeks
5mg USD 1,900.00 2 weeks
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Related CAS #
No Data
Synonym
Spinosyn A aglycone
IUPAC/Chemical Name
(2R,3aS,5aR,5bS,9S,13S,14R,16aS,16bR)-9-ethyl-2,13-dihydroxy-14-methyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-1H-as-indaceno[3,2-d][1]oxacyclododecine-7,15-dione
InChi Key
DIHUILSVOGYVDG-MRAVEKNJSA-N
InChi Code
InChI=1S/C24H34O5/c1-3-16-5-4-6-22(26)13(2)24(28)21-11-19-17(20(21)12-23(27)29-16)8-7-14-9-15(25)10-18(14)19/h7-8,11,13-20,22,25-26H,3-6,9-10,12H2,1-2H3/t13-,14-,15-,16+,17-,18-,19-,20+,22+/m1/s1
SMILES Code
O[C@H]([C@@H](C)C1=O)CCC[C@H](CC)OC(C[C@]2([H])C1=C[C@]3([H])[C@@]2([H])C=C[C@@]4([H])[C@@]3([H])C[C@H](O)C4)=O
Appearance
Solid powder
Purity
>95% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
To be determined
Shelf Life
>3 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info
Product Data
Product Data
Instruction
View handling instruction
Biological target:
Spinosyn A aglycone has no insecticidal activity at concentrations up to 64 ppm.
In vitro activity:
The tri-O-methylrhamnose at the 9-position of the 17-pseudoaglycone of spinosyn A was hydrolyzed under more vigorous acidic conditions to give the aglycone of spinosyn A. Reference: J Antibiot (Tokyo). 1998 Aug;51(8):795-800. https://pubmed.ncbi.nlm.nih.gov/9766471/
In vivo activity:
To be determined

Preparing Stock Solutions

The following data is based on the product molecular weight 402.53 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
Formulation protocol:
1. Creemer LC, Kirst HA, Paschal JW. Conversion of spinosyn A and spinosyn D to their respective 9- and 17-pseudoaglycones and their aglycones. J Antibiot (Tokyo). 1998 Aug;51(8):795-800. doi: 10.7164/antibiotics.51.795. PMID: 9766471.
In vitro protocol:
1. Creemer LC, Kirst HA, Paschal JW. Conversion of spinosyn A and spinosyn D to their respective 9- and 17-pseudoaglycones and their aglycones. J Antibiot (Tokyo). 1998 Aug;51(8):795-800. doi: 10.7164/antibiotics.51.795. PMID: 9766471.
In vivo protocol:
To be determined
1. Creemer, L.C., Kirst, H.A., and Paschal, J.W. Conversion of spinosyn A and spinosyn D to their respective 9- and 17-pseudoaglycones and their aglycones. J. Antibiot. (Tokyo) 51(8), 795-800 (1998).

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