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MedKoo Cat#: 531414 | Name: Formetanate

Description:

WARNING: This product is for research use only, not for human or veterinary use.

Formetanate isa bioactive chemical.

Chemical Structure

Formetanate
Formetanate
CAS#22259-30-9

Theoretical Analysis

MedKoo Cat#: 531414

Name: Formetanate

CAS#: 22259-30-9

Chemical Formula: C11H15N3O2

Exact Mass: 221.1164

Molecular Weight: 221.26

Elemental Analysis: C, 59.71; H, 6.83; N, 18.99; O, 14.46

Price and Availability

This product is currently not in stock but may be available through custom synthesis. To ensure cost efficiency, the minimum order quantity is 1 gram. The estimated lead time is 2 to 4 months, with pricing dependent on the complexity of the synthesis (typically high for intricate chemistries). Quotes for quantities below 1 gram will not be provided. To request a quote, please click the button below. Note: If this product becomes available in stock in the future, pricing will be listed accordingly.
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Related CAS #
No Data
Synonym
Formetanate
IUPAC/Chemical Name
Carbamic acid, methyl-, ester with N'-(m-hydroxyphenyl)-N,N-dimethylformamidine
InChi Key
RMFNNCGOSPBBAD-MDWZMJQESA-N
InChi Code
InChI=1S/C11H15N3O2/c1-12-11(15)16-10-6-4-5-9(7-10)13-8-14(2)3/h4-8H,1-3H3,(H,12,15)/b13-8+
SMILES Code
CN(C)/C=N/C1=CC=CC(OC(NC)=O)=C1
Appearance
Solid powder
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>3 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 221.26 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1: Gao X, Sun Y, You H, Dai Y, Guo H, Zhao Q. Simultaneous determination of amitraz, chlordimeform, formetanate and metabolites in human blood by liquid chromatography tandem mass spectrometry with phospholipid-removal pretreatment. Biomed Chromatogr. 2018 Dec 22:e4477. doi: 10.1002/bmc.4477. [Epub ahead of print] PubMed PMID: 30578570. 2: Piel C, Pouchieu C, Migault L, Béziat B, Boulanger M, Bureau M, Carles C, Grüber A, Lecluse Y, Rondeau V, Schwall X, Tual S, Lebailly P, Baldi I; AGRICAN group . Increased risk of central nervous system tumours with carbamate insecticide use in the prospective cohort AGRICAN. Int J Epidemiol. 2018 Nov 23. doi: 10.1093/ije/dyy246. [Epub ahead of print] PubMed PMID: 30476073. 3: Wu Y, Guo H, Bu J, Tan Y, Zhong J, Zhao Q. Rapid and sensitive determination of formamidines and metabolites with HPLC-MS/MS using core-shell columns. J Chromatogr B Analyt Technol Biomed Life Sci. 2018 Feb 15;1076:22-28. doi: 10.1016/j.jchromb.2018.01.012. PubMed PMID: 29406027. 4: Beloti VH, Alves GR, Moral RA, Demétrio CGB, Yamamoto PT. Acute Toxicity of Fresh and Aged Residues of Pesticides to the Parasitoid Tamarixia radiata and to the HLB-Bacteria Vector Diaphorina citri. Neotrop Entomol. 2018 Jun;47(3):403-411. doi: 10.1007/s13744-017-0575-2. Epub 2017 Dec 8. PubMed PMID: 29222706. 5: Kobayashi M, Sakai N, Kamijo K, Koike H, Nemoto S, Shindo T. Determination of Formetanate Hydrochloride in Agricultural Products by LC-MS/MS. Shokuhin Eiseigaku Zasshi. 2017;58(5):221-228. doi: 10.3358/shokueishi.58.221. Japanese. PubMed PMID: 29081458. 6: Franco AA, Zanardi OZ, Jacob CRO, de Oliveira MBR, Yamamoto PT. Susceptibility of Euseius concordis (Mesostigmata: Phytoseiidae) to pesticides used in citrus production systems. Exp Appl Acarol. 2017 Sep;73(1):61-77. doi: 10.1007/s10493-017-0176-0. Epub 2017 Sep 2. PubMed PMID: 28866797. 7: Staroň M, Sabo R, Sobeková A, Sabová L, Legáth J, Lohajová Ľ, Javorský P. Formetanate toxicity and changes in antioxidant enzyme system of Apis mellifera larvae. Environ Sci Pollut Res Int. 2017 Jun;24(16):14060-14070. doi: 10.1007/s11356-017-8966-9. Epub 2017 Apr 13. PubMed PMID: 28409431. 8: Gao X, Tan Y, Guo H. Simultaneous determination of amitraz, chlordimeform, formetanate and their main metabolites in human urine by high performance liquid chromatography-tandem mass spectrometry. J Chromatogr B Analyt Technol Biomed Life Sci. 2017 May 1;1052:27-33. doi: 10.1016/j.jchromb.2017.03.004. Epub 2017 Mar 11. PubMed PMID: 28346886. 9: Gallart-Mateu D, Armenta S, de la Guardia M. Indoor and outdoor determination of pesticides in air by ion mobility spectrometry. Talanta. 2016 Dec 1;161:632-639. doi: 10.1016/j.talanta.2016.09.020. Epub 2016 Sep 6. PubMed PMID: 27769458. 10: Melnyk LJ, Wang Z, Li Z, Xue J. Prioritization of pesticides based on daily dietary exposure potential as determined from the SHEDS model. Food Chem Toxicol. 2016 Oct;96:167-73. doi: 10.1016/j.fct.2016.07.025. Epub 2016 Aug 4. PubMed PMID: 27497764. 11: Martins AC, Ribeiro FW, Zanatta G, Freire VN, Morais S, de Lima-Neto P, Correia AN. Modeling of laccase inhibition by formetanate pesticide using theoretical approaches. Bioelectrochemistry. 2016 Apr;108:46-53. doi: 10.1016/j.bioelechem.2015.12.004. Epub 2015 Dec 21. PubMed PMID: 26720841. 12: Podhorniak LV. The use of dispersive pipet extraction (DPX) tips for the sample cleanup of apples, pears, and oranges in the analysis of formetanate HCI. J AOAC Int. 2014 May-Jun;97(3):942-5. PubMed PMID: 25051648. 13: Guillén J, Navarro M, Bielza P. Cross-resistance and baseline susceptibility of spirotetramat in Frankliniella occidentalis (Thysanoptera: Thripidae). J Econ Entomol. 2014 Jun;107(3):1239-44. PubMed PMID: 25026688. 14: Oliveira TM, Barroso MF, Morais S, Araújo M, Freire C, de Lima-Neto P, Correia AN, Oliveira MB, Delerue-Matos C. Sensitive bi-enzymatic biosensor based on polyphenoloxidases-gold nanoparticles-chitosan hybrid film-graphene doped carbon paste electrode for carbamates detection. Bioelectrochemistry. 2014 Aug;98:20-9. doi: 10.1016/j.bioelechem.2014.02.003. Epub 2014 Mar 5. PubMed PMID: 24642204. 15: Ribeiro FW, Barroso MF, Morais S, Viswanathan S, de Lima-Neto P, Correia AN, Oliveira MB, Delerue-Matos C. Simple laccase-based biosensor for formetanate hydrochloride quantification in fruits. Bioelectrochemistry. 2014 Feb;95:7-14. doi: 10.1016/j.bioelechem.2013.09.005. Epub 2013 Oct 8. PubMed PMID: 24161938. 16: Oliveira TM, Fátima Barroso M, Morais S, Araújo M, Freire C, de Lima-Neto P, Correia AN, Oliveira MB, Delerue-Matos C. Laccase-Prussian blue film-graphene doped carbon paste modified electrode for carbamate pesticides quantification. Biosens Bioelectron. 2013 Sep 15;47:292-9. doi: 10.1016/j.bios.2013.03.026. Epub 2013 Mar 21. PubMed PMID: 23587791. 17: Moser VC, Padilla S, Simmons JE, Haber LT, Hertzberg RC. Impact of chemical proportions on the acute neurotoxicity of a mixture of seven carbamates in preweanling and adult rats. Toxicol Sci. 2012 Sep;129(1):126-34. doi: 10.1093/toxsci/kfs190. Epub 2012 May 30. PubMed PMID: 22649187. 18: López-Soler N, Cervera A, Quinto V, Abellán J, Bielza P, Martínez-Pardo R, Garcerá MD. Esterase inhibition by synergists in the western flower thrips Frankliniella occidentalis. Pest Manag Sci. 2011 Dec;67(12):1549-56. doi: 10.1002/ps.2211. Epub 2011 Jun 8. PubMed PMID: 21656898. 19: Contreras J, Espinosa PJ, Quinto V, Abellán J, Grávalos C, Fernández E, Bielza P. Life-stage variation in insecticide resistance of the western flower thrips (Thysanoptera: Thripidae). J Econ Entomol. 2010 Dec;103(6):2164-8. PubMed PMID: 21309240. 20: Nault BA, Shelton AM. Impact of insecticide efficacy on developing action thresholds for pest management: a case study of onion thrips (Thysanoptera: Thripidae) on onion. J Econ Entomol. 2010 Aug;103(4):1315-26. Erratum in: J Econ Entomol. 2010 Oct;103(5):v. PubMed PMID: 20857743.

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