MedKoo Cat#: 581675 | Name: Decaborane
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Description:

WARNING: This product is for research use only, not for human or veterinary use.

Decaborane, also called decaborane(14), is the borane with the chemical formula B10H14. This white crystalline compound is one of the principal boron hydride clusters, both as a reference structure and as a precursor to other boron hydrides. On its own, Decaborane is able to undergo reduction via acetate as a neat liquid.

Chemical Structure

Decaborane
Decaborane
CAS#17702-41-9

Theoretical Analysis

MedKoo Cat#: 581675

Name: Decaborane

CAS#: 17702-41-9

Chemical Formula: B10H14

Exact Mass: 124.2026

Molecular Weight: 122.21

Elemental Analysis: B, 88.45; H, 11.55

Price and Availability

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1g USD 750.00 2 Weeks
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Related CAS #
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Synonym
Boron hydride (B10H14); Decaborane; Decaborane (B10H14); Tetradecahydrodecaborane; nido-Decaborane(14); NSC-39828; NSC 39828; NSC39828;
IUPAC/Chemical Name
Decaboron tetradecahydride;
InChi Key
XAMMYYSPUSIWAS-UHFFFAOYSA-N
InChi Code
InChI=1S/B10H14/c11-5-1-2-3(1,5)7(2,9(3,5,11)13-7)8(2)4(1,2)6(1,5)10(4,8,12-6)14-8/h1-10H
SMILES Code
[BH]1234[BH]567[BH]18([BH]59%10[BH]%11%128[BH]9%13%14[H][BH]%106%14[H]7)[BH]2%15%11[BH]%12%13%16[BH]%153([H]%16)[H]4
Appearance
Solid powder
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>3 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 122.21 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1: Li J, Cao K, Li J, Liu M, Zhang S, Yang J, Zhang Z, Li B. Synthesis and Ceramic Conversion of a New Organodecaborane Preceramic Polymer with High-Ceramic-Yield. Molecules. 2018 Sep 26;23(10). pii: E2461. doi: 10.3390/molecules23102461. PubMed PMID: 30261601; PubMed Central PMCID: PMC6222739. 2: Pérez S, Sanz Miguel PJ, Macías R. Decaborane anion tautomerism: ion pairing and proton transfer control. Dalton Trans. 2018 Apr 24;47(16):5850-5859. doi: 10.1039/c8dt00610e. PubMed PMID: 29649346. 3: Qian L, Ma KY, Zhou ZJ, Ma F. Design of a catalyst through Fe doping of the boron cage B(10)H(14) for CO(2) hydrogenation and investigation of the catalytic character of iron hydride (Fe-H). Phys Chem Chem Phys. 2017 Dec 13;19(48):32723-32732. doi: 10.1039/c7cp05953a. PubMed PMID: 29199289. 4: Schmidt MW, Gordon MS. Effect of Boron Clusters on the Ignition Reaction of HNO(3) and Dicynanamide-Based Ionic Liquids. J Phys Chem A. 2017 Oct 19;121(41):8003-8011. doi: 10.1021/acs.jpca.7b07996. Epub 2017 Oct 6. PubMed PMID: 28922914. 5: Rachiero GP, Titi HM, Rogers RD. Versatility and remarkable hypergolicity of exo-6, exo-9 imidazole-substituted nido-decaborane. Chem Commun (Camb). 2017 Jul 6;53(55):7736-7739. doi: 10.1039/c7cc03322b. PubMed PMID: 28649688. 6: Balagurova EV, Pisareva IV, Smol'yakov AF, Dolgushin FM, Godovikov IA, Chizhevsky IT. Distorted commo-Cobaltacarboranes Based on the 5,6-Dicarba-nido-decaborane(12): The First Bimetal Cobalt-Copper Zwitterion-Containing Cluster with Four (B-H)(4)···Cu Bonds Not Showing Fluxional Behavior in Solution. Inorg Chem. 2016 Nov 7;55(21):11193-11200. Epub 2016 Oct 12. PubMed PMID: 27731627. 7: Nishino K, Yamamoto H, Tanaka K, Chujo Y. Development of Solid-State Emissive Materials Based on Multifunctional o-Carborane-Pyrene Dyads. Org Lett. 2016 Aug 19;18(16):4064-7. doi: 10.1021/acs.orglett.6b01920. Epub 2016 Jul 29. PubMed PMID: 27471860. 8: Xiong H, Zhou D, Qi Y, Zhang Z, Xie Z, Chen X, Jing X, Meng F, Huang Y. Doxorubicin-Loaded Carborane-Conjugated Polymeric Nanoparticles as Delivery System for Combination Cancer Therapy. Biomacromolecules. 2015 Dec 14;16(12):3980-8. doi: 10.1021/acs.biomac.5b01311. Epub 2015 Nov 23. PubMed PMID: 26564472. 9: Liu JB, Li PJ, Chen YF, Wang ZG, Qi F, He JR, Zheng BJ, Zhou JH, Zhang WL, Gu L, Li YR. Observation of tunable electrical bandgap in large-area twisted bilayer graphene synthesized by chemical vapor deposition. Sci Rep. 2015 Oct 16;5:15285. doi: 10.1038/srep15285. PubMed PMID: 26472497; PubMed Central PMCID: PMC4607884. 10: Gona KB, Thota JL, Baz Z, Gómez-Vallejo V, Llop J. Straightforward synthesis of radioiodinated Cc-substituted o-carboranes: towards a versatile platform to enable the in vivo assessment of BNCT drug candidates. Dalton Trans. 2015 Jun 7;44(21):9915-20. doi: 10.1039/c5dt01049g. PubMed PMID: 25939694. 11: Boggio P, Toppino A, Geninatti Crich S, Alberti D, Marabello D, Medana C, Prandi C, Venturello P, Aime S, Deagostino A. The hydroboration reaction as a key for a straightforward synthesis of new MRI-NCT agents. Org Biomol Chem. 2015 Mar 21;13(11):3288-97. doi: 10.1039/c4ob02291b. PubMed PMID: 25645198. 12: Li Y, Xu HL, Zhong RL, Sun SL, Su ZM. The Effect of the different spin multiplicity on nonlinear optical properties of lithium decahydroborate dimers. J Mol Model. 2014 Sep;20(9):2415. doi: 10.1007/s00894-014-2415-1. Epub 2014 Sep 13. PubMed PMID: 25213111. 13: Ferrer-Ugalde A, González-Campo A, Viñas C, Rodríguez-Romero J, Santillan R, Farfán N, Sillanpää R, Sousa-Pedrares A, Núñez R, Teixidor F. Fluorescence of new o-carborane compounds with different fluorophores: can it be tuned? Chemistry. 2014 Aug 4;20(32):9940-51. doi: 10.1002/chem.201402396. Epub 2014 Jun 26. PubMed PMID: 24976049. 14: McCrary PD, Barber PS, Kelley SP, Rogers RD. Nonaborane and decaborane cluster anions can enhance the ignition delay in hypergolic ionic liquids and induce hypergolicity in molecular solvents. Inorg Chem. 2014 May 5;53(9):4770-6. doi: 10.1021/ic500622f. Epub 2014 Apr 9. PubMed PMID: 24716643. 15: Yu XH, Cao K, Huang Y, Yang J, Li J, Chang G. Platinum catalyzed sequential hydroboration of decaborane: a facile approach to poly(alkenyldecaborane) with decaborane in the mainchain. Chem Commun (Camb). 2014 May 7;50(35):4585-7. doi: 10.1039/c3cc49203f. PubMed PMID: 24667965. 16: Nakamura H, Tasaki L, Kanoh D, Sato S, Ban HS. Diaryl-substituted ortho-carboranes as a new class of hypoxia inducible factor-1α inhibitors. Dalton Trans. 2014 Apr 7;43(13):4941-4. doi: 10.1039/c3dt52828f. PubMed PMID: 24270971. 17: Muhammad S, Xu H, Su Z, Fukuda K, Kishi R, Shigeta Y, Nakano M. A new type of organic-inorganic hybrid NLO-phore with large off-diagonal first hyperpolarizability tensors: a two-dimensional approach. Dalton Trans. 2013 Nov 14;42(42):15053-62. doi: 10.1039/c3dt51331a. Epub 2013 Sep 2. PubMed PMID: 23995975. 18: Chatterjee S, Carroll PJ, Sneddon LG. Iridium and ruthenium catalyzed syntheses, hydroborations, and metathesis reactions of alkenyl-decaboranes. Inorg Chem. 2013 Aug 5;52(15):9119-30. doi: 10.1021/ic401356u. Epub 2013 Jul 16. PubMed PMID: 23859100. 19: Ringstrand B, Kaszynski P. Functionalization of the [closo-1-CB9H10]- anion for the construction of new classes of liquid crystals. Acc Chem Res. 2013 Feb 19;46(2):214-25. doi: 10.1021/ar300081b. Epub 2012 Oct 25. PubMed PMID: 23098274. 20: Roy DK, Bose SK, Anju RS, Ramkumar V, Ghosh S. Synthesis and structure of dirhodium analogue of octaborane-12 and decaborane-14. Inorg Chem. 2012 Oct 15;51(20):10715-22. doi: 10.1021/ic301070e. Epub 2012 Sep 21. PubMed PMID: 22998603.