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MedKoo Cat#: 581366 | Name: Cloransulam-methyl

Description:

WARNING: This product is for research use only, not for human or veterinary use.

Cloransulam-methyl is a herbicide.

Chemical Structure

Cloransulam-methyl
Cloransulam-methyl
CAS#147150-35-4

Theoretical Analysis

MedKoo Cat#: 581366

Name: Cloransulam-methyl

CAS#: 147150-35-4

Chemical Formula: C15H13ClFN5O5S

Exact Mass: 429.0310

Molecular Weight: 429.81

Elemental Analysis: C, 41.92; H, 3.05; Cl, 8.25; F, 4.42; N, 16.29; O, 18.61; S, 7.46

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Synonym
Cloransulam-methyl; Cloransulam methyl; DE 565; DE565; DE-565; Cloransulam methyl ester; FirstRate; Chloransulam-methyl
IUPAC/Chemical Name
Methyl 3-chloro-2-(((5-ethoxy-7-fluoro(1,2,4)triazolo(1,5-c)pyrimidin-2-yl)sulfonyl)amino)benzoate
InChi Key
BIKACRYIQSLICJ-UHFFFAOYSA-N
InChi Code
InChI=1S/C15H13ClFN5O5S/c1-3-27-15-18-10(17)7-11-19-14(20-22(11)15)28(24,25)21-12-8(13(23)26-2)5-4-6-9(12)16/h4-7,21H,3H2,1-2H3
SMILES Code
O=C(OC)C1=CC=CC(Cl)=C1NS(=O)(C2=NN3C(OCC)=NC(F)=CC3=N2)=O
Appearance
Solid powder
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>3 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.03.00
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 429.81 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1: Zhang Y, Zhang J, Shi B, Li B, Du Z, Wang J, Zhu L, Wang J. Effects of cloransulam-methyl and diclosulam on soil nitrogen and carbon cycle-related microorganisms. J Hazard Mater. 2021 Sep 15;418:126395. doi: 10.1016/j.jhazmat.2021.126395. Epub 2021 Jun 12. PMID: 34329028. 2: Zhang Z, Li M, Feng M, Zhu K, Han L. Dissipation dynamics and final residues of cloransulam-methyl in soybean and soil. Environ Monit Assess. 2016 Mar;188(3):168. doi: 10.1007/s10661-016-5168-8. Epub 2016 Feb 16. PMID: 26884355. 3: Wu R, Liu H, Lu C, Hou K, Wang X, Wang J, Du Z, Li B, Zhu L, Wang J. The effect of TiO2NPs on cloransulam-methyl toxicity to earthworm (Eisenia fetida). Chemosphere. 2023 May;322:138242. doi: 10.1016/j.chemosphere.2023.138242. Epub 2023 Feb 23. PMID: 36841449. 4: Krieger MS, Wynn JL, Yoder RN. Extraction of cloransulam-methyl from soil with subcritical water and supercritical CO2. J Chromatogr A. 2000 Nov 3;897(1-2):405-13. doi: 10.1016/s0021-9673(00)00818-9. PMID: 11128225. 5: Lewer P, Finney-Brink KL, Duebelbeis DO. Nature of the residue of [(14)C]Cloransulam-methyl in lactating goats. J Agric Food Chem. 2000 Jun;48(6):2532-46. doi: 10.1021/jf9909611. PMID: 10888581. 6: Vital Silva V, Mendes R, Suzukawa A, Adegas F, Marcelino-Guimaraes F, Oliveira R Jr. A Target-Site Mutation Confers Cross-Resistance to ALS-Inhibiting Herbicides in Erigeron sumatrensis from Brazil. Plants (Basel). 2022 Feb 9;11(4):467. doi: 10.3390/plants11040467. PMID: 35214801; PMCID: PMC8879965. 7: Johnson TC, Martin TP, Mann RK, Pobanz MA. Penoxsulam--structure-activity relationships of triazolopyrimidine sulfonamides. Bioorg Med Chem. 2009 Jun 15;17(12):4230-40. doi: 10.1016/j.bmc.2009.02.010. Epub 2009 Feb 14. PMID: 19464188. 8: Rodriguez-Delgado MA, Hernández-Borges J. Rapid analysis of triazolopyrimidine sulfoanilide herbicides in waters and soils by high- performance liquid chromatography with UV detection using a C18 monolithic column. J Sep Sci. 2007 Jan;30(1):8-14. doi: 10.1002/jssc.200600271. PMID: 17313135. 9: Hernández-Borges J, García-Montelongo FJ, Cifuentes A, Rodríguez-Delgado MA. Analysis of triazolopyrimidine herbicides in soils using field-enhanced sample injection-coelectroosmotic capillary electrophoresis combined with solid-phase extraction. J Chromatogr A. 2005 Dec 30;1100(2):236-42. doi: 10.1016/j.chroma.2005.09.053. Epub 2005 Oct 5. PMID: 16212970. 10: Barnes ER, Knezevic SZ, Sikkema PH, Lindquist JL, Jhala AJ. Control of Glyphosate-Resistant Common Ragweed (Ambrosia artemisiifolia L.) in Glufosinate-Resistant Soybean [Glycine max (L.) Merr]. Front Plant Sci. 2017 Aug 18;8:1455. doi: 10.3389/fpls.2017.01455. PMID: 28868065; PMCID: PMC5563374. 11: Pfleeger T, Olszyk D, Plocher M, Yilma S. Effects of low concentrations of herbicides on full-season, field-grown potatoes. J Environ Qual. 2008 Oct 23;37(6):2070-82. doi: 10.2134/jeq2007.0376. PMID: 18948460. 12: Hernández-Borges J, Rodriguez-Delgado MA, García-Montelongo FJ, Cifuentes A. Analysis of pesticides in soy milk combining solid-phase extraction and capillary electrophoresis-mass spectrometry. J Sep Sci. 2005 Jun;28(9-10):948-56. doi: 10.1002/jssc.200500014. PMID: 16013821. 13: McKelvey RA, Wright JP, Honegger JL. A comparison of crop and non-crop plants as sensitive indicator species for regulatory testing. Pest Manag Sci. 2002 Dec;58(12):1161-74. doi: 10.1002/ps.504. PMID: 12476989. 14: Hernández-Borges J, García-Montelongo FJ, Cifuentes A, Rodríguez-Delgado MA. Determination of herbicides in mineral and stagnant waters at ng/L levels using capillary electrophoresis and UV detection combined with solid-phase extraction and sample stacking. J Chromatogr A. 2005 Apr 8;1070(1-2):171-7. doi: 10.1016/j.chroma.2005.02.053. PMID: 15861801.

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