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MedKoo Cat#: 461012 | Name: Prosulfocarb
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Description:

WARNING: This product is for research use only, not for human or veterinary use.

Prosulfocarb is a widely used thiocarbamate herbicide in winter cereals. Prosulfocarb is a relevant aerosol precursor under OH radicals (OH) photooxidation conditions.

Chemical Structure

Prosulfocarb
Prosulfocarb
CAS#52888-80-9

Theoretical Analysis

MedKoo Cat#: 461012

Name: Prosulfocarb

CAS#: 52888-80-9

Chemical Formula: C14H21NOS

Exact Mass: 251.1344

Molecular Weight: 251.38

Elemental Analysis: C, 66.89; H, 8.42; N, 5.57; O, 6.36; S, 12.75

Price and Availability

Size Price Availability Quantity
250mg USD 435.00
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Related CAS #
No Data
Synonym
Prosulfocarb; SC 0574; SC-0574; SC0574; Arkade
IUPAC/Chemical Name
S-benzyl dipropylcarbamothioate
InChi Key
NQLVQOSNDJXLKG-UHFFFAOYSA-N
InChi Code
InChI=1S/C14H21NOS/c1-3-10-15(11-4-2)14(16)17-12-13-8-6-5-7-9-13/h5-9H,3-4,10-12H2,1-2H3
SMILES Code
O=C(SCC1=CC=CC=C1)N(CCC)CCC
Appearance
Solid powder
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>3 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.03.00
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 251.38 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1: Vinck AK, Felkers E, Urtizberea M, Hewitt NJ, Bürling K, Morriss A. Ambient air concentrations of plant protection products: Data collection for the combined air concentration database and associated risk assessment. Regul Toxicol Pharmacol. 2024 May;149:105627. doi: 10.1016/j.yrtph.2024.105627. Epub 2024 Apr 15. PMID: 38621522. 2: Slaby S, Catteau A, Le Cor F, Cant A, Dufour V, Iurétig A, Turiès C, Palluel O, Bado-Nilles A, Bonnard M, Cardoso O, Dauchy X, Porcher JM, Banas D. Chemical occurrence of pesticides and transformation products in two small lentic waterbodies at the head of agricultural watersheds and biological responses in caged Gasterosteus aculeatus. Sci Total Environ. 2023 Dec 15;904:166326. doi: 10.1016/j.scitotenv.2023.166326. Epub 2023 Aug 16. PMID: 37591395. 3: Schaad E, Fracheboud M, Droz B, Kast C. Quantitation of pesticides in bee bread collected from honey bee colonies in an agricultural environment in Switzerland. Environ Sci Pollut Res Int. 2023 Apr;30(19):56353-56367. doi: 10.1007/s11356-023-26268-y. Epub 2023 Mar 14. PMID: 36917390; PMCID: PMC10121494. 4: Lebrun JD, El Kouch S, Guenne A, Tournebize J. Screening potential toxicity of currently used herbicides in the freshwater amphipod Gammarus fossarum based on multi-level biomarker responses to field-realistic exposures. Environ Pollut. 2023 Mar 1;320:120985. doi: 10.1016/j.envpol.2022.120985. Epub 2022 Dec 30. PMID: 36592881. 5: Nanusha MY, Frøkjær EE, Liigand J, Christensen MR, Hansen HR, Hansen M. Unravelling the occurrence of trace contaminants in surface waters using semi- quantitative suspected non-target screening analyses. Environ Pollut. 2022 Dec 15;315:120346. doi: 10.1016/j.envpol.2022.120346. Epub 2022 Oct 3. PMID: 36202272. 6: EFSA (European Food Safety Authority); Bellisai G, Bernasconi G, Brancato A, Carrasco Cabrera L, Castellan I, Ferreira L, Giner G, Greco L, Jarrah S, Leuschner R, Magrans JO, Miron I, Nave S, Pedersen R, Reich H, Robinson T, Ruocco S, Santos M, Scarlato AP, Theobald A, Verani A. Modification of the existing maximum residue levels for prosulfocarb in herbs and edible flowers. EFSA J. 2022 May 18;20(5):e07334. doi: 10.2903/j.efsa.2022.7334. PMID: 35600271; PMCID: PMC9115684. 7: Zaller JG, Kruse-Plaß M, Schlechtriemen U, Gruber E, Peer M, Nadeem I, Formayer H, Hutter HP, Landler L. Pesticides in ambient air, influenced by surrounding land use and weather, pose a potential threat to biodiversity and humans. Sci Total Environ. 2022 Sep 10;838(Pt 2):156012. doi: 10.1016/j.scitotenv.2022.156012. Epub 2022 May 18. PMID: 35597361; PMCID: PMC7614392. 8: Brühl CA, Bakanov N, Köthe S, Eichler L, Sorg M, Hörren T, Mühlethaler R, Meinel G, Lehmann GUC. Direct pesticide exposure of insects in nature conservation areas in Germany. Sci Rep. 2021 Dec 16;11(1):24144. doi: 10.1038/s41598-021-03366-w. PMID: 34916546; PMCID: PMC8677746. 9: Malviya BK, Verma VP, Sharma S. Electrochemical metal- and oxidant-free synthesis of S-thiocarbamates. Org Biomol Chem. 2021 Nov 10;19(43):9491-9500. doi: 10.1039/d1ob01701b. PMID: 34709281. 10: Slaby S, Le Cor F, Dufour V, Auger L, Pasquini L, Cardoso O, Curtet L, Baudoin JM, Wiest L, Vulliet E, Feidt C, Dauchy X, Banas D. Distribution of pesticides and some of their transformation products in a small lentic waterbody: Fish, water, and sediment contamination in an agricultural watershed. Environ Pollut. 2022 Jan 1;292(Pt B):118403. doi: 10.1016/j.envpol.2021.118403. Epub 2021 Oct 23. PMID: 34699920. 11: Busi R, Beckie HJ, Bates A, Boyes T, Davey C, Haskins B, Mock S, Newman P, Porri A, Onofri A. Herbicide resistance across the Australian continent. Pest Manag Sci. 2021 Nov;77(11):5139-5148. doi: 10.1002/ps.6554. Epub 2021 Jul 31. PMID: 34260812. 12: Akhter MJ, M Abdurruhman A, Mathiassen SK, Kudsk P. Low Effectiveness of Prosulfocarb and Mesosulfuron-Methyl + Iodosulfuron-Methyl against Vulpia myuros. Plants (Basel). 2021 Jun 10;10(6):1186. doi: 10.3390/plants10061186. PMID: 34200907; PMCID: PMC8230502. 13: Dufour V, Wiest L, Slaby S, Le Cor F, Auger L, Cardoso O, Curtet L, Pasquini L, Dauchy X, Vulliet E, Banas D. Miniaturization of an extraction protocol for the monitoring of pesticides and polar transformation products in biotic matrices. Chemosphere. 2021 Dec;284:131292. doi: 10.1016/j.chemosphere.2021.131292. Epub 2021 Jun 23. PMID: 34198062. 14: Torra J, Montull JM, Taberner A, Onkokesung N, Boonham N, Edwards R. Target- Site and Non-target-Site Resistance Mechanisms Confer Multiple and Cross- Resistance to ALS and ACCase Inhibiting Herbicides in Lolium rigidum From Spain. Front Plant Sci. 2021 Feb 4;12:625138. doi: 10.3389/fpls.2021.625138. PMID: 33613607; PMCID: PMC7889805. 15: Busi R, Goggin DE, Onofri A, Boutsalis P, Preston C, Powles SB, Beckie HJ. Loss of trifluralin metabolic resistance in Lolium rigidum plants exposed to prosulfocarb recurrent selection. Pest Manag Sci. 2020 Dec;76(12):3926-3934. doi: 10.1002/ps.5993. Epub 2020 Aug 7. PMID: 32638493. 16: Mobli A, Rinwa A, Sahil, Chauhan BS. Effects of sorghum residue in presence of pre-emergence herbicides on emergence and biomass of Echinochloa colona and Chloris virgata. PLoS One. 2020 Mar 2;15(3):e0229817. doi: 10.1371/journal.pone.0229817. Erratum in: PLoS One. 2022 Mar 10;17(3):e0265522. doi: 10.1371/journal.pone.0265522. PMID: 32119693; PMCID: PMC7051094. 17: Bo X, Sun J, Mei Q, Wei B, An Z, Han D, Li Z, Xie J, Zhan J, He M. Degradation of prosulfocarb by hydroxyl radicals in gas and aqueous phase: Mechanisms, kinetics and toxicity. Ecotoxicol Environ Saf. 2020 Mar 15;191:110175. doi: 10.1016/j.ecoenv.2020.110175. Epub 2020 Jan 16. PMID: 31954924. 18: Devault DA, Guillemin JP, Millet M, Eymery F, Hulin M, Merlo M. Prosulfocarb at center stage! Environ Sci Pollut Res Int. 2022 Jan;29(1):61-67. doi: 10.1007/s11356-019-06928-8. Epub 2019 Nov 23. PMID: 31760619. 19: Barba V, Marín-Benito JM, Sánchez-Martín MJ, Rodríguez-Cruz MS. Transport of 14C-prosulfocarb through soil columns under different amendment, herbicide incubation and irrigation regimes. Sci Total Environ. 2020 Jan 20;701:134542. doi: 10.1016/j.scitotenv.2019.134542. Epub 2019 Oct 23. PMID: 31734489. 20: Barba V, Marín-Benito JM, García-Delgado C, Sánchez-Martín MJ, Rodríguez- Cruz MS. Assessment of 14C-prosulfocarb dissipation mechanism in soil after amendment and its impact on the microbial community. Ecotoxicol Environ Saf. 2019 Oct 30;182:109395. doi: 10.1016/j.ecoenv.2019.109395. Epub 2019 Jul 1. PMID: 31272022.

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