MedKoo Cat#: 161238 | Name: Zn(II) Octaethylporphine
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Description:

WARNING: This product is for research use only, not for human or veterinary use.

Zn(II) Octaethylporphine is a synthetic porphyrin product with supramolecular properties. Zn(II) Octaethylporphine is used to make a phototransistor with a field-effect transistor configuration.

Chemical Structure

Zn(II) Octaethylporphine
Zn(II) Octaethylporphine
CAS#17632-18-7

Theoretical Analysis

MedKoo Cat#: 161238

Name: Zn(II) Octaethylporphine

CAS#: 17632-18-7

Chemical Formula: C36H44N4Zn

Exact Mass: 596.2857

Molecular Weight: 598.16

Elemental Analysis: C, 72.29; H, 7.41; N, 9.37; Zn, 10.93

Price and Availability

Size Price Availability Quantity
100mg USD 485.00 2 Weeks
250mg USD 720.00 2 Weeks
1g USD 1,280.00 2 Weeks
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Related CAS #
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Synonym
Zn(II) Octaethylporphyrin; Zn (II) Octaethylporphyrin; Zn(II) Octaethylporphine; Zn (II) Octaethylporphine;
IUPAC/Chemical Name
n/a
InChi Key
VVUVWOLOUOYXOI-XTPDIVBZSA-N
InChi Code
InChI=1S/C36H44N4.Zn/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;/h17-20H,9-16H2,1-8H3;/q-2;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;
SMILES Code
CCC1=C(C2=N/C1=C\C(N3[Zn]N(/C4=C\2)/C(C(CC)=C4CC)=C\C5=N/C(C(CC)=C5CC)=C\C3=C6CC)=C6CC)CC
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 598.16 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1.) Yoshimoto, et al. Controlled molecular orientation in an adlayer of a supramolecular assembly consisting of an open-cage C60 derivative and ZnII octaethylporphyrin on Au(111). Angewandte Chemie – International Edition, 2004, vol. 43, # 23, p. 3044 – 3047. https://doi.org/10.1002/anie.200453959 2.) Schweitzer, et al. Mechanism of photosensitized generation of singlet oxygen during oxygen quenching of triplet states and the general dependence of the rate constants and efficiencies. Journal of Physical Chemistry A, 2003, vol. 107, # 13, p. 2192 – 2198. https://doi.org/10.1021/jp026189d 3.) Liu, et al. Photophysics of soret-excited tetrapyrroles in solution. II. Effects of perdeuteration, substituent nature and position, and macrocycle structure and conformation in zinc(II) porphyrins. Journal of Physical Chemistry A, 2008, vol. 112, # 38, p. 8986 – 8998. https://doi.org/10.1021/jp804792x 4.) Amashukeli, et al. Inner-sphere electron-transfer reorganization energies of zinc porphyrins. Journal of the American Chemical Society, 2004, vol. 126, # 47, p. 15566 – 15571. https://doi.org/10.1021/ja0351037 5.) Ji, et al. ZnOEP based phototransistor: Signal amplification and light-controlled switch. Chemical Communications, 2008, # 23, p. 2653 – 2655. https://doi.org/10.1039/B805204B 6.) Yoshimoto, et al. Supramolecular assembly of [60] fullerene and highly ordered zinc octaethylporphyrin adlayer formed on Au(111) surface. Chemistry Letters, 2004, vol. 33, # 7, p. 914 – 915. https://doi.org/10.1246/cl.2004.914