Synonym
XDN74807; XDN-74807; XDN 74807; Zn(II) meso-Tetraphenylporphine (chlorin free); Zn(II) meso-Tetraphenylporphyrin (chlorin free); Zn (II) meso-Tetraphenylporphine (chlorin free); Zn (II) meso-Tetraphenylporphyrin (chlorin free);
InChi Key
XPVVGUHKLPZAEN-DAJBKUBHSA-N
InChi Code
InChI=1S/C44H28N4.Zn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;/h1-28H;/q-2;+2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;
SMILES Code
C1(/C2=C3N4/C(C=C/3)=C(C5=N/C(C=C5)=C(C6=CC=C(/C(C7=CC=CC=C7)=C8N=C2C=C\8)N6[Zn]4)/C9=CC=CC=C9)/C%10=CC=CC=C%10)=CC=CC=C1
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
678.12
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Chen, et al. Cyanide-Selective Electrode Based on Zn(II) Tetraphenylporphyrin as Ionophore. Anal. Chem. 2012, 84, 21, 9192–9198. https://doi.org/10.1021/ac301910c
2.) Xu, H., Zhang, M., Ding, H. et al. Colloidal silica beads modified with quantum dots and zinc (II) tetraphenylporphyrin for colorimetric sensing of ammonia. Microchim Acta 180, 85–91 (2013). https://doi.org/10.1007/s00604-012-0914-2
3.) Magdaong, et al. Photophysical Properties and Electronic Structure of Zinc(II) Porphyrins Bearing 0–4 meso-Phenyl Substituents: Zinc Porphine to Zinc Tetraphenylporphyrin (ZnTPP). J. Phys. Chem. A 2020, 124, 38, 7776–7794. https://doi.org/10.1021/acs.jpca.0c06841
4.) Awwad, et al. Visible-Light-Initiated Free-Radical Polymerization by Homomolecular Triplet-Triplet Annihilation. Chem. Volume 6, Issue 11, 5 November 2020, Pages 3071-3085. https://doi.org/10.1016/j.chempr.2020.08.019
