Synonym
SHN76085; SHN-76085; SHN 76085; Zn(II) meso-Tetra(pentafluorophenyl) porphine; Zn(II) meso-Tetra(pentafluorophenyl) porphyrin; Zn (II) meso-Tetra(pentafluorophenyl) porphine; Zn (II) meso-Tetra(pentafluorophenyl) porphyrin;
InChi Key
SITWILXFZRVHNL-HQJDZOCDSA-N
InChi Code
InChI=1S/C44H8F20N4.Zn/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;/h1-8H;/q-2;+2/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;
SMILES Code
FC(C(F)=C(F)C(F)=C1F)=C1/C(C(C=C/2)=NC2=C3C4=C(F)C(F)=C(F)C(F)=C4F)=C5N6/C(C=C/5)=C(C7=N/C(C=C7)=C(C8=CC=C\3N8[Zn]6)/C9=C(F)C(F)=C(F)C(F)=C9F)/C%10=C(F)C(F)=C(F)C(F)=C%10F
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
1,037.92
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Ma, et al. Effects of fluorination in the ring of zinc tetraphenylporphyrin on its gas-response to volatiles at room temperature. Sensors and Actuators B: Chemical. Volume 114, Issue 2, 26 April 2006, Pages 1035-1042. https://doi.org/10.1016/j.snb.2005.07.073
2.) Spellane, et al. Porphyrins. 40. Electronic spectra and four-orbital energies of free-base, zinc, copper, and palladium tetrakis(perfluorophenyl)porphyrins. Inorganic Chemistry, 1980, vol. 19, # 2, p. 386 – 391. https://doi.org/10.1021/ic50204a021
3.) Lei, et al. First-row transition metal porphyrins for electrocatalytic hydrogen evolution – a SPP/JPP Young Investigator Award paper. Journal of Porphyrins and Phthalocyanines, 2020, vol. 24, # 11-12, p. 1361 – 1371. https://doi.org/10.1142/S1088424620500157
