Synonym
XNL34850; XNL-34850; XNL 34850; Sn(IV) meso-Tetraphenylporphine dichloride (contains 1-3% chlorin); Sn (IV) meso-Tetraphenylporphine dichloride (contains 1-3% chlorin)
IUPAC/Chemical Name
14,14-dichloro-4,9,16,22-tetraphenyl-14H-5,8-(azeno)-1,12-(metheno[2]epipyrrolometheno)dipyrrolo[1,2-c:2',1'-k][1,3]diaza[2]stannacycloundecine
InChi Key
XUDRSQMCBSITKE-NBICUONBSA-L
InChi Code
InChI=1S/C44H28N4.2ClH.Sn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;;/h1-28H;2*1H;/q-2;;;+4/p-2/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;;
SMILES Code
Cl[Sn]1(Cl)N2/C3=C(C4=CC=CC=C4)\C5=N/C(C=C5)=C(C6=CC=CC=C6)\C7=CC=C(N17)/C(C8=CC=CC=C8)=C9N=C(C=C\9)/C(C%10=CC=CC=C%10)=C2/C=C3
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
802.35
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Zhong, et al. Interfacial Self-Assembly Driven Formation of Hierarchically Structured Nanocrystals with Photocatalytic Activity. ACS Nano 2014, 8, 1, 827–833. https://doi.org/10.1021/nn405492d
2.) Baral, et al. Tin(IV)-Porphyrin Tetracarbonyl Cobaltate: An Efficient Catalyst for the Carbonylation of Epoxides. Catalysts 2019, 9(4), 311; https://doi.org/10.3390/catal9040311
3.) Johnson, et al. Porphyrin-Metalation-Mediated Tuning of Photoredox Catalytic Properties in Metal-Organic Frameworks. ACS Catalysis, 2015, vol. 5, # 9, p. 5283 – 5291. https://doi.org/10.1021/acscatal.5b00941
4.) Moghadam, et al. Rapid and efficient acetylation of alcohols and phenols with acetic anhydride catalyzed by electron-deficient tin(IV) porphyrin. Journal of Molecular Catalysis A: Chemical, 2004, vol. 219, # 1, p. 73 – 78. https://doi.org/10.1016/j.molcata.2007.05.012
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6.) Arnold, et al. Tin porphyrins. 6. Tin-119 chemical shifts and line widths of tin(IV) complexes of tetraphenyl-, tetra-p-tolyl-, and octaethylporphyrin. Inorganic Chemistry, 1994, vol. 33, # 7, p. 1486 – 1490. https://doi.org/10.1021/ic00085a044
7.) Maiti, et al. Photophysics of soret-excited tetrapyrroles in solution. IV. Radiationless decay and triplet-triplet annihilation investigated using tetraphenylporphinato Sn(IV). Journal of Physical Chemistry A, 2009, vol. 113, # 42, p. 11318 – 11326. https://doi.org/10.1021/jp906966h
8.) Olsson, et al. Design of oxophilic metalloporphyrins: An experimental and DFT study of methanol binding. Dalton Transactions, 2018, vol. 47, # 33, p. 11572 – 11585. https://doi.org/10.1039/C8DT02432D
