Synonym
Pd(II) Octaethylporphyrin; Pd (II) Octaethylporphyrin; Pd (II) Octaethylporphine; Pd(II) Octaethylporphine;
InChi Key
FVPOYVGWFFRIHG-XTPDIVBZSA-N
InChi Code
InChI=1S/C36H44N4.Pd/c1-9-21-22(10-2)30-18-32-25(13-5)26(14-6)34(39-32)20-36-28(16-8)27(15-7)35(40-36)19-33-24(12-4)23(11-3)31(38-33)17-29(21)37-30;/h17-20H,9-16H2,1-8H3;/q-2;+2/b29-17-,30-18-,31-17-,32-18-,33-19-,34-20-,35-19-,36-20-;
SMILES Code
CCC1=C2N3[Pd]N4/C(C(CC)=C(/C4=C/C(C(CC)=C/5CC)=NC5=C/2)CC)=C\C(C(CC)=C/6CC)=NC6=C/C3=C1CC
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
639.20
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Ju, et al. A novel low-powered upconversion strategy to enhance the anti-Stokes shift: cascading one-photon hot-band absorption and triplet sensitization based on Pd(ii)octaethylporphyrin. J. Mater. Chem. C, 2021,9, 6749-6753. https://doi.org/10.1039/D1TC00721A
2.) Wang, et al. A high-performance optical trace oxygen sensor based on the room-temperature phosphorescence from palladium (II) octaethylporphyrin. Measurement. Volume 206, January 2023, 112275. https://doi.org/10.1016/j.measurement.2022.112275
3.) Haefele, et al. Getting to the (Square) Root of the Problem: How to Make Noncoherent Pumped Upconversion Linear. J. Phys. Chem. Lett. 2012, 3, 3, 299–303. https://doi.org/10.1021/jz300012u
4.) Singh, et al. Phosphorescence spectra and triplet state lifetimes of palladium octaethylporphyrin, palladium octaethylchlorin and palladium 2,3-dimethyloctaethylisobacteriochlorin at 77 K. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. Volume 59, Issue 5, 15 March 2003, Pages 905-908. https://doi.org/10.1016/S1386-1425(02)00258-5
