Synonym
MYM95554; MYM-95554; MYM 95554; Mn(III) meso-Tetraphenylporphine chloride (1-3% chlorin);
InChi Key
MIUMWNDEIWVIEG-YKKPBKTHSA-M
InChi Code
InChI=1S/C44H28N4.ClH.Mn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;
SMILES Code
Cl[Mn]1N2/C3=C(C4=N/C(C=C4)=C(C5=CC=C(/C(C6=CC=CC=C6)=C7N=C(/C(C8=CC=CC=C8)=C2/C=C3)C=C\7)N15)/C9=CC=CC=C9)/C%10=CC=CC=C%10
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
703.12
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Al-Muntaser, et al. Tuning structural, optical, and dispersion functions of polystyrene via addition of meso-tetraphenylporphine manganese (III) chloride towards optoelectronic applications. Optical Materials, Volume 135, January 2023, 113333. https://doi.org/10.1016/j.optmat.2022.113333
2.) Attia, et al. Studies on structural and optical properties of thermally evaporated nanocrystalline thin films of meso-Tetraphenylporphyrin manganese(III) chloride. Journal of Luminescence. Volume 199, July 2018, Pages 391-399.
2.) Merlau, et al. Anthracene-Induced Turnover Enhancement in the Manganese Porphyrin-Catalyzed Epoxidation of Olefins. Inorg. Chem. 2005, 44, 15, 5523–5529. https://doi.org/10.1021/ic0505596
3.) Mahmoudi, et al. Water increases rates of epoxidation by Mn(iii)porphyrins/imidazole/IO4- in CH2Cl2. Analogy with peroxidase and chloride dismutase. Dalton Trans., 2011,40, 8695-8700. https://doi.org/10.1039/C1DT10689A
4.) Guo, et al. Spectroscopic observation of iodosylarene metalloporphyrin adducts and manganese(V)-oxo porphyrin species in a cytochrome P450 analogue. Nature Communications volume 3, Article number: 1190 (2012). https://doi.org/10.1038/ncomms2196
5.) Alzabny, et al. Mn(III) and Fe(III) Porphyrin Complexes as Electrocatalysts for Hydrogen Evolution Reaction: A comparative study.Int. J. Electrochem. Sci., 16 (2021). 10.20964/2021.07.24
6.) Yuan, et al. Efficient oxidative coupling of amines to imines catalyzed by manganese(III) meso-tetraphenylporphyrin chloride under ambient conditions. Catalysis Communications. Volume 12, Issue 3, 30 November 2010, Pages 202-206. https://doi.org/10.1016/j.catcom.2010.09.009
7.) Chen, et al. A novel histidine assay using tetraphenylporphyrin manganese (III) chloride as a molecular recognition probe by resonance light scattering technique. Analytica Chimica Acta. Volume 570, Issue 1, 7 June 2006, Pages 109-115. https://doi.org/10.1016/j.aca.2006.04.003
