Synonym
ZVM68437; ZVM-68437; ZVM 68437; Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride
InChi Key
ZUWLFJDGJIEKOF-VTVSBRCESA-M
InChi Code
InChI=1S/C44H8F20N4.ClH.Mn/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;;/h1-8H;1H;/q-2;;+3/p-1/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;;
SMILES Code
Cl[Mn]1N2/C(C=C/C2=C(C3=C(F)C(F)=C(F)C(F)=C3F)/C(C=C/4)=NC4=C5\C6=C(F)C(F)=C(F)C(F)=C6F)=C(C7=C(F)C(F)=C(F)C(F)=C7F)\C8=N/C(C=C8)=C(C9=C(F)C(F)=C(F)C(F)=C9F)\C%10=CC=C5N1%10
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
1,062.93
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Gallo, et al. The use of modified electrodes by hybrid systems gold nanoparticles/Mn-porphyrin in electrochemical detection of cysteine. Synthetic Metals. Volume 198, December 2014, Pages 335-339. https://doi.org/10.1016/j.synthmet.2014.10.024
2.) Pinto, et al. A biocompatible redox MRI probe based on a Mn(ii)/Mn(iii) porphyrin. Dalton Trans., 2019,48, 3249-3262. https://doi.org/10.1039/C8DT04775H
3.) Battioni, et al.An easy access to polyhalogenated metalloporphyrins covalently bound to polymeric supports as efficient catalysts for hydrocarbon oxidation. J. Chem. Soc., Chem. Commun., 1992, 1051-1053. https://doi.org/10.1039/C39920001051
4.) Jung, et al. Photocatalytic Oxygenation of 10-Methyl-9,10-dihydroacridine by O2with Manganese Porphyrins. J. Phys. Chem. A 2014, 118, 32, 6223–6229. https://doi.org/10.1021/jp505860f
5.) Yu, et al. Amidation of Saturated C−H Bonds Catalyzed by Electron-Deficient Ruthenium and Manganese Porphyrins. A Highly Catalytic Nitrogen Atom Transfer Process. Org. Lett. 2000, 2, 15, 2233–2236. https://doi.org/10.1021/ol000107r