Synonym
DWM39497; DWM-39497; DWM 39497; Mn(III) meso-Tetra(2,4,6-trimethylphenyl)porphine chloride;
InChi Key
DJRQGDJTRUAUPG-WSJWEZPUSA-M
InChi Code
InChI=1S/C56H52N4.ClH.Mn/c1-29-21-33(5)49(34(6)22-29)53-41-13-15-43(57-41)54(50-35(7)23-30(2)24-36(50)8)45-17-19-47(59-45)56(52-39(11)27-32(4)28-40(52)12)48-20-18-46(60-48)55(44-16-14-42(53)58-44)51-37(9)25-31(3)26-38(51)10;;/h13-28H,1-12H3;1H;/q-2;;+3/p-1/b53-41+,53-42+,54-43+,54-45+,55-44+,55-46+,56-47+,56-48+;;
SMILES Code
CC1=C(C(C)=CC(C)=C1)/C2=C3C=C/C4=C(C5=C(C)C=C(C=C5C)C)/C6=N/C(C=C6)=C(C7=C(C)C=C(C=C7C)C)\C8=CC=C(N8[Mn](Cl)N\34)/C(C9=C(C)C=C(C=C9C)C)=C%10N=C2C=C\%10
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
871.45
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Sap, et al. Synthesis of 18F-difluoromethylarenes using aryl boronic acids, ethyl bromofluoroacetate and [18F]fluoride. Chem. Sci., 2019, 10, 3237-3241. 10.1039/C8SC05096A
2.) Sorokin, et al. Intramolecular kinetic isotope effects in alkane hydroxylations catalyzed by manganese and iron porphyrin complexes. J. Am. Chem. Soc. 1993, 115, 16, 7293–7299. https://doi.org/10.1021/ja00069a031
3.) Nakagaki, et al. Relevance of the reaction of a manganese(III) chelate with hydroxide ion to photosynthesis: Reaction of hydroxide ion with 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)porphinatomanganese(III) in ligating and non ligating solvents. Proc. Natl. Acad. Sci. USA Vol. 85, pp. 5424-5428, August 1988.
4.) van der Made, et al. Effect of Ph on the Epoxidation of Alkenes by the Cytochrome-P-450 Model Manganese(Iii) Porphyrin Hypochlorite. Recueil des Travaux Chimiques des Pays-Bas. Volume 108, Issue 5, 1989,Pages 185-188. https://doi.org/10.1002/recl.19891080505
