Synonym
TYN56819; TYN 56819; TYN-56819; meso-Tetra[4-(allyloxy)phenyl] porphine; 5,10,15,20-tetrakis(4-(allyloxy)phenyl)porphyrin;
IUPAC/Chemical Name
5,10,15,20-tetrakis(4-(allyloxy)phenyl)porphyrin
InChi Key
TXPIYPFMEBQQFI-YFLSTINXSA-N
InChi Code
InChI=1S/C56H46N4O4/c1-5-33-61-41-17-9-37(10-18-41)53-45-25-27-47(57-45)54(38-11-19-42(20-12-38)62-34-6-2)49-29-31-51(59-49)56(40-15-23-44(24-16-40)64-36-8-4)52-32-30-50(60-52)55(48-28-26-46(53)58-48)39-13-21-43(22-14-39)63-35-7-3/h5-32,57,60H,1-4,33-36H2/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-
SMILES Code
C=CCOC1=CC=C(/C2=C3N/C(C=C/3)=C(C4=N/C(C=C4)=C(C5=CC=C(OCC=C)C=C5)\C6=CC=C(N6)/C(C7=CC=C(OCC=C)C=C7)=C8N=C2C=C\8)/C9=CC=C(OCC=C)C=C9)C=C1
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
839.01
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Zhang, et al. A general method for constructing optically active supramolecular assemblies from intrinsically achiral water-insoluble free-base porphyrins. Chemistry – A European Journal, 2008, vol. 14, # 6, p. 1793 – 1803. https://doi.org/10.1002/chem.200701333
2.) Ozbek, et al. The use of porphyrins in potentiometric sensors as ionophores. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2020, vol. 98, # 1-2. https://doi.org/10.1007/s10847-020-01004-y
3.) Cabrera-Gonzalez, et al. High-Boron-Content Porphyrin-Cored Aryl Ether Dendrimers: Controlled Synthesis, Characterization, and Photophysical Properties. Inorganic Chemistry, 2015, vol. 54, # 10, p. 5021 – 5031. https://doi.org/10.1021/acs.inorgchem.5b00618
4.) Taranu, et al. Catalytic Properties of Free-Base Porphyrin Modified Graphite Electrodes for Electrochemical Water Splitting in Alkaline Medium. Processes, 2022, vol. 10, # 3, art. no. 611. https://doi.org/10.3390/pr10030611
