HLN09542 | CAS# 14609-54-2 | Synthetic porphyrin

MedKoo Cat#: 161174 | Name: HLN09542

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Description:

WARNING: This product is for research use only, not for human or veterinary use.

HLN09542, also known as meso-Tetra(4-carboxyphenyl)porphine is a synthetic porphyrin derivative. HLN09542 is a essential component of the construction of many metal organic frameworks and synthetic organic frameworks. HLN09542 is a photosensitizer used in solar energy conversion. This product has no formal name at the moment. For the convenience of communication, a temporal code name was therefore proposed according to MedKoo Chemical Nomenclature (see web page: https://www.medkoo.com/page/naming)

Chemical Structure

HLN09542

CAS#14609-54-2

Theoretical Analysis

MedKoo Cat#: 161174

Name: HLN09542

CAS#: 14609-54-2

Chemical Formula: C48H30N4O8

Exact Mass: 790.2064

Molecular Weight: 790.79

Elemental Analysis: C, 72.91; H, 3.82; N, 7.09; O, 16.19

Price and Availability

Size	Price	Availability
250mg	USD 430.00	2 Weeks
500mg	USD 600.00	2 Weeks
1g	USD 790.00	2 Weeks

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Related CAS #

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Synonym

HLN09542; HLN-09542; HLN 09542; meso-Tetra(4-carboxyphenyl)porphine; 4,4',4'',4'''-(porphyrin-5,10,15,20-tetrayl)tetrabenzoic acid;

IUPAC/Chemical Name

4,4',4'',4'''-(porphyrin-5,10,15,20-tetrayl)tetrabenzoic acid

InChi Key

HHDUMDVQUCBCEY-LWQDQPMZSA-N

InChi Code

InChI=1S/C48H30N4O8/c53-45(54)29-9-1-25(2-10-29)41-33-17-19-35(49-33)42(26-3-11-30(12-4-26)46(55)56)37-21-23-39(51-37)44(28-7-15-32(16-8-28)48(59)60)40-24-22-38(52-40)43(36-20-18-34(41)50-36)27-5-13-31(14-6-27)47(57)58/h1-24,49,52H,(H,53,54)(H,55,56)(H,57,58)(H,59,60)/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

SMILES Code

O=C(O)C(C=C1)=CC=C1/C(C2=CC=C3N2)=C4N=C(C=C/4)/C(C5=CC=C(C(O)=O)C=C5)=C6C=C/C(N/6)=C(C(C=C/7)=NC7=C3\C8=CC=C(C(O)=O)C=C8)\C9=CC=C(C(O)=O)C=C9

Appearance

To be determined

Purity

>98% (or refer to the Certificate of Analysis)

Shipping Condition

Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition

Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).

Solubility

To be determined

Shelf Life

>2 years if stored properly

Drug Formulation

To be determined

Stock Solution Storage

0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code

2934.99.9001

More Info

Instruction

View handling instruction

Preparing Stock Solutions

The following data is based on the product molecular weight 790.79 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Concentration / Solvent Volume / Mass	1 mg	5 mg	10 mg
1 mM	1.15 mL	5.76 mL	11.51 mL
5 mM	0.23 mL	1.15 mL	2.3 mL
10 mM	0.12 mL	0.58 mL	1.15 mL
50 mM	0.02 mL	0.12 mL	0.23 mL

1.) Rajasree, S.S., Li, X., Deria, P.; Physical Properties of Porphyrin-based crystalline metal-organic frameworks. Communications Chemistry 4, 47, 2021. https://doi.org/10.1038/s42004-021-00484-4 2.) Chen, J., Zhu, Y., Kaskel, S.; Porphyrin-Based Metal_Organic Frameworks for Biomedical Applications. Angew. Chemie. Int. Ed. 2021, 60, 5010-5035. https://doi.org/10.1002/anie.201909880 3.) Moradi, E., Rahimi, R., Farahani, Y.D., Safarifard, V.; Porphyrinic zirconium-based MOF with exposed pyrrole Lewis base site as a luminescent sensor for highly selective sensing of Cd2+ and Br- ions and THF small molecule. Journal of Solid State Chemistry 2020, 282, 121103. https://doi.org/10.1016/j.jssc.2019.121103 4.) Jia, Y., Li, F., Jia, T., Wang, Z.; Meso-tetra(4-carboxyphenyl)porphine-Enhanced DMA Methylation Sensing Interface on a Light-Addressable Potentiometric Sensor. ACS Omega 2019, 4, 7, 12567-12574. https://doi.org/10.1021/acsomega.9b00980 5.) Elzi, D.J., Bauta, W.E., Sanchez, J.R., Das, T., Mogare, S., Fatland, P.Z., Iza, M., Pertsemlidis, A., Rebel, V.T.; Identification of a novel mechanism for meso-tetra(4-carboxyphenyl) porphyrin (TCPP) uptake in cancer cells. The FASEB Journal. 2021;35:e21427. https://doi.org/10.1096/fj.202000197R 6.) Sanchez-Munoz, E., Garate-Morales, J.L, Sandoval-Lira, J., Hernandez-Perez, J.M., Aguilar-Sanchez, R.; Porphyrin Supramolecular Arrays Fromed by Weakly Intereacting Meso-Functional Groups on Au(111). Molecules 2019, 24(18), 3326; https://doi.org/10.3390/molecules24183326 7.) Cherian, S., Wamser, C.C.; Adsorption and Photoactivity of Tetra(4-carboxyphenyl)porphyrin (TCPP) on Nanoparticulate TiO2. J. Phys. Chem. B 2000, 104, 15, 3624–3629. https://doi.org/10.1021/jp994459v