Synonym
KLN12772; KLN 12772; KLN-12772; meso-Tetra (4-chlorophenyl) porphine; 5,10,15,20-tetrakis(4-chlorophenyl)porphyrin;
IUPAC/Chemical Name
5,10,15,20-tetrakis(4-chlorophenyl)porphyrin
InChi Key
KLMHOLCGHWVPMP-LWQDQPMZSA-N
InChi Code
InChI=1S/C44H26Cl4N4/c45-29-9-1-25(2-10-29)41-33-17-19-35(49-33)42(26-3-11-30(46)12-4-26)37-21-23-39(51-37)44(28-7-15-32(48)16-8-28)40-24-22-38(52-40)43(36-20-18-34(41)50-36)27-5-13-31(47)14-6-27/h1-24,49,52H/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-
SMILES Code
ClC1=CC=C(C=C1)/C2=C(C=C/3)/NC3=C(C(C=C/4)=NC4=C(C5=CC=C(C=C5)Cl)/C6=CC=C(N6)/C(C7=CC=C(C=C7)Cl)=C8N=C2C=C\8)\C9=CC=C(C=C9)Cl
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
752.52
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Wang, et al. Controlling the Nature of Mixed (Phthalocyaninato)(porphyrinato) Rare-Earth(III) Double-Decker Complexes: The Effects of Nonperipheral Alkoxy Substitution of the Phthalocyanine Ligand. Chemistry, A European Journal. Volume 12, Issue 5, February 1, 2006, Pages 1475-1485. https://doi.org/10.1002/chem.200500733
2.) Kan, et al. Sandwich-Type Mixed Tetrapyrrole Rare-Earth Triple-Decker Compounds. Effect of the Coordination Geometry on the Single-Molecule-Magnet Nature. Inorg. Chem. 2013, 52, 15, 8505–8510. https://doi.org/10.1021/ic400485y
3.) Belcher, et al. Porphyrin complexes containing coordinated BOB groups: synthesis, chemical reactivity and the structure of [BOB(tpClpp)]2+. Dalton Trans., 2008, 1602-1614. https://doi.org/10.1039/B716189A
4.) Zhu, et al. Effect of substituent groups of porphyrins on the electroluminescent properties of porphyrin-doped OLED devices. Journal of Physical Organic Chemistry. Volume 23, Issue 3, March 2010, Pages 190-194.
5.) Guergueb, et al. Effect of the coordination of π-acceptor 4-cyanopyridine ligand on the structural and electronic properties of meso-tetra(para-methoxy) and meso-tetra(para-chlorophenyl) porphyrin cobalt(ii) coordination compounds. Application in the catalytic degradation of methylene blue dye. RSC Adv., 2020,10, 6900-6918. https://doi.org/10.1039/C9RA08504A
