Synonym
ZHM95207; ZHM-95207; ZHM 95207; Fe(III) meso-Tetra(4-methoxyphenyl) porphine chloride; Fe (III) meso-Tetra(4-methoxyphenyl) porphine chloride;
InChi Key
ZZRDTBXKIGUTNH-HTMHXADGSA-M
InChi Code
InChI=1S/C48H36N4O4.ClH.Fe/c1-53-33-13-5-29(6-14-33)45-37-21-23-39(49-37)46(30-7-15-34(54-2)16-8-30)41-25-27-43(51-41)48(32-11-19-36(56-4)20-12-32)44-28-26-42(52-44)47(40-24-22-38(45)50-40)31-9-17-35(55-3)18-10-31;;/h5-28H,1-4H3;1H;/q-2;;+3/p-1/b45-37-,45-38-,46-39-,46-41-,47-40-,47-42-,48-43-,48-44-;;
SMILES Code
Cl[Fe](N1/C(C=C/C1=C(C2=CC=C(C=C2)OC)/C3=N/C(C=C3)=C4/C5=CC=C(C=C5)OC)=C6/C7=CC=C(C=C7)OC)N8C4=CC=C8/C(C9=CC=C(C=C9)OC)=C%10N=C6C=C\%10
Appearance
To be determined
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).
Solubility
To be determined
Shelf Life
>2 years if stored properly
Drug Formulation
To be determined
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
824.14
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
1.) Wolf, et al. Shape and stereoselective cyclopropanation of alkenes catalyzed by iron porphyrins. J. Am. Chem. Soc. 1995, 117, 36, 9194–9199. https://doi.org/10.1021/ja00141a011
2.) Baumann, et al. Iron Porphyrin Catalyzed N−H Insertion Reactions with Ethyl Diazoacetate. Organometallics 2007, 26, 16, 3995–4002. https://doi.org/10.1021/om0610997
3.) Guo, et al. A new evidence of the high-valent oxo–metal radical cation intermediate and hydrogen radical abstract mechanism in hydrocarbon hydroxylation catalyzed by metalloporphyrins. Journal of Molecular Catalysis A: Chemical. Volume 157, Issues 1–2, 20 June 2000, Pages 31-40. https://doi.org/10.1016/S1381-1169(99)00444-6
4.) Wang, et al. A Green Process for Oxidation of p-Nitrotoluene Catalyzed by Metalloporphyrins under Mild Conditions. Org. Process Res. Dev. 2006, 10, 4, 757–761. https://doi.org/10.1021/op060056z
5.) Gericke, et al. Oxo-Free Hydrocarbon Oxidation by an Iron(III)-Isoporphyrin Complex. Inorg. Chem. 2020, 59, 19, 13952–13961. https://doi.org/10.1021/acs.inorgchem.0c01618
6.) Lu, et al. Dioxygen reduction catalyzed by substituted iron tetraphenylporphyrins in acidic media. Journal of Porphyrins and Phthalocyanines. Vol. 16, No. 03, pp. 310-315 (2012). https://doi.org/10.1142/S1088424612500356
