Haloxyfop-p-methyl ester | proherbicide | herbicide | enantiomer | CAS#72619-32-0

MedKoo Cat#: 125484 | Name: Haloxyfop-p-methyl ester

Description:

WARNING: This product is for research use only, not for human or veterinary use.

Haloxyfop-p-methyl ester, a selective herbicide, is used to control a wide range of annual and perennial grass weeds in broad-leaved crops, such as legume, cotton, peanut, rape, and vegetables.

Chemical Structure

Haloxyfop-p-methyl ester

CAS#72619-32-0

Theoretical Analysis

MedKoo Cat#: 125484

Name: Haloxyfop-p-methyl ester

CAS#: 72619-32-0

Chemical Formula: C16H13ClF3NO4

Exact Mass: 375.0500

Molecular Weight: 375.73

Elemental Analysis: C, 51.15; H, 3.49; Cl, 9.44; F, 15.17; N, 3.73; O, 17.03

Price and Availability

This product is currently not in stock but may be available through custom synthesis. To ensure cost efficiency, the minimum order quantity is 1 gram. The estimated lead time is 2 to 4 months, with pricing dependent on the complexity of the synthesis (typically high for intricate chemistries). Quotes for quantities below 1 gram will not be provided. To request a quote, please click the button below. Note: If this product becomes available in stock in the future, pricing will be listed accordingly.

Bulk Inquiry

Related CAS #

No Data

Synonym

Haloxyfop-P-methyl; 72619-32-0; Gallant Super; (R)-Methyl 2-(4-((3-chloro-5-(trifluoromethyl)pyridin-2-yl)oxy)phenoxy)propanoate Eloge

IUPAC/Chemical Name

methyl (R)-2-(4-((3-chloro-5-(trifluoromethyl)pyridin-2-yl)oxy)phenoxy)propanoate

InChi Key

MFSWTRQUCLNFOM-SECBINFHSA-N

InChi Code

InChI=1S/C16H13ClF3NO4/c1-9(15(22)23-2)24-11-3-5-12(6-4-11)25-14-13(17)7-10(8-21-14)16(18,19)20/h3-9H,1-2H3/t9-/m1/s1

SMILES Code

COC(=O)[C@@H](C)OC1=CC=C(OC2=C(Cl)C=C(C=N2)C(F)(F)F)C=C1

Appearance

To be determined

Purity

>98% (or refer to the Certificate of Analysis)

Shipping Condition

Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition

Dry, dark and at 0 -4 C for short term (days to weeks) or -20 C for long term(months to years).

Solubility

To be determined

Shelf Life

>2 years if stored properly

Drug Formulation

To be determined

Stock Solution Storage

0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code

2934.99.9001

More Info

Instruction

View handling instruction

Preparing Stock Solutions

The following data is based on the product molecular weight 375.73 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Concentration / Solvent Volume / Mass	1 mg	5 mg	10 mg
1 mM	1.15 mL	5.76 mL	11.51 mL
5 mM	0.23 mL	1.15 mL	2.3 mL
10 mM	0.12 mL	0.58 mL	1.15 mL
50 mM	0.02 mL	0.12 mL	0.23 mL

1: Liu X, Hou Z, Zhang Y, Merchant A, Zhong ME, Ma G, Zeng Q, Wu L, Zhou X, Luo K, Ding C. Cloning and functional characterization of a tau class glutathione transferase associated with haloxyfop-P-methyl resistance in Digitaria sanguinalis. Pest Manag Sci. 2023 Oct;79(10):3950-3958. doi: 10.1002/ps.7588. Epub 2023 Jun 28. PMID: 37248658. 2: Xu W, Yang Y, Tian J, Du X, Ye Y, Liu Z, Li Y, Zhao Y. Integrated physiological and transcriptome analysis reveals potential toxicity mechanism of haloxyfop-P-methyl to Chiromantes dehaani. Environ Pollut. 2023 Aug 15;331(Pt 1):121879. doi: 10.1016/j.envpol.2023.121879. Epub 2023 May 23. PMID: 37230172. 3: de Oliveira Mendes B, Mesak C, Calixto JED Jr, Malafaia G. Mice exposure to haloxyfop-p-methyl ester at predicted environmentally relevant concentrations leads to anti-predatory response deficit. Environ Sci Pollut Res Int. 2018 Nov;25(31):31762-31770. doi: 10.1007/s11356-018-3222-5. Epub 2018 Sep 21. PMID: 30242651. 4: Olayinka ET, Ore A. Hepatotoxicity, Nephrotoxicity and Oxidative Stress in Rat Testis Following Exposure to Haloxyfop-p-methyl Ester, an Aryloxyphenoxypropionate Herbicide. Toxics. 2015 Oct 15;3(4):373-389. doi: 10.3390/toxics3040373. PMID: 29051470; PMCID: PMC5606644. 5: Bao H, Fang S, Liu Z, Shi H, Ye Y, Wang M. Development of an enzyme-linked immunosorbent assay for the rapid detection of haloxyfop-P-methyl. J Agric Food Chem. 2010 Jul 28;58(14):8167-70. doi: 10.1021/jf101152m. PMID: 20593822. 6: Yu Y, Zhao S, Yang Y, Chen Y, Qiu D, Ran X, Lu P, Hu D. Simultaneous Determination of Rimsulfuron and Haloxyfop-P-methyl and Its Metabolite Haloxyfop in Tobacco Leaf by LC-MS/MS. J AOAC Int. 2019 Sep 1;102(5):1632-1640. doi: 10.5740/jaoacint.18-0280. Epub 2019 Jan 23. PMID: 30674371. 7: Park S, Lee JY, Park H, Song G, Lim W. Haloxyfop-P-methyl induces developmental defects in zebrafish embryos through oxidative stress and anti- vasculogenesis. Comp Biochem Physiol C Toxicol Pharmacol. 2020 Jul;233:108761. doi: 10.1016/j.cbpc.2020.108761. Epub 2020 Apr 11. PMID: 32289526. 8: Xu W, Yang Y, Tian J, Du X, Ye Y, Liu Z, Li Y, Zhao Y. Haloxyfop-P-methyl induces immunotoxicity and glucose metabolism disorders and affects the Nrf2/ARE pathway mediated antioxidant system in Chiromantes dehaani. Environ Pollut. 2023 Oct 15;335:122332. doi: 10.1016/j.envpol.2023.122332. Epub 2023 Aug 7. PMID: 37558200. 9: Liu Y, Guo J, Liu W, Yang F, Deng Y, Meng Y, Cheng B, Fu J, Zhang J, Liao X, Wei L, Lu H. Effects of haloxyfop-p-methyl on the developmental toxicity, neurotoxicity, and immunotoxicity in zebrafish. Fish Shellfish Immunol. 2023 Jan;132:108466. doi: 10.1016/j.fsi.2022.108466. Epub 2022 Dec 1. PMID: 36462742.