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MedKoo Cat#: 463342 | Name: Tribenuron-methyl
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Description:

WARNING: This product is for research use only, not for human or veterinary use.

Tribenuron methyl is the methyl ester of tribenuron. It has a role as a herbicide. It is a methoxy-1,3,5-triazine, a N-sulfonylurea and a methyl ester. It derives from a tribenuron.

Chemical Structure

Tribenuron-methyl
Tribenuron-methyl
CAS#101200-48-0

Theoretical Analysis

MedKoo Cat#: 463342

Name: Tribenuron-methyl

CAS#: 101200-48-0

Chemical Formula: C15H17N5O6S

Exact Mass: 395.0900

Molecular Weight: 395.39

Elemental Analysis: C, 45.57; H, 4.33; N, 17.71; O, 24.28; S, 8.11

Price and Availability

Size Price Availability Quantity
100mg USD 550.00 2 Weeks
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Related CAS #
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Synonym
Tribenuron-methyl; Tribenuron methyl; Cameo; Express;
IUPAC/Chemical Name
methyl 2-(N-((4-methoxy-6-methyl-1,3,5-triazin-2-yl)(methyl)carbamoyl)sulfamoyl)benzoate
InChi Key
VLCQZHSMCYCDJL-UHFFFAOYSA-N
InChi Code
InChI=1S/C15H17N5O6S/c1-9-16-13(18-14(17-9)26-4)20(2)15(22)19-27(23,24)11-8-6-5-7-10(11)12(21)25-3/h5-8H,1-4H3,(H,19,22)
SMILES Code
COC(c1c(S(=O)(NC(N(c2nc(OC)nc(C)n2)C)=O)=O)cccc1)=O
Appearance
Solid powder
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>3 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 395.39 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1: Guarda PM, Pontes AMS, Domiciano RS, Gualberto LDS, Mendes DB, Guarda EA, da Silva JEC. Assessment of Ecological Risk and Environmental Behavior of Pesticides in Environmental Compartments of the Formoso River in Tocantins, Brazil. Arch Environ Contam Toxicol. 2020 Nov 4. doi: 10.1007/s00244-020-00770-7. Epub ahead of print. PMID: 33150460. 2: Spilsbury FD, Warne MSJ, Backhaus T. Risk Assessment of Pesticide Mixtures in Australian Rivers Discharging to the Great Barrier Reef. Environ Sci Technol. 2020 Nov 2. doi: 10.1021/acs.est.0c04066. Epub ahead of print. PMID: 33136377. 3: Prudnikova S, Streltsova N, Volova T. The effect of the pesticide delivery method on the microbial community of field soil. Environ Sci Pollut Res Int. 2020 Oct 16. doi: 10.1007/s11356-020-11228-7. Epub ahead of print. PMID: 33064277. 4: Volova T, Shumilova A, Zhila N, Sukovatyi A, Shishatskaya E, Thomas S. Efficacy of Slow-Release Formulations of Metribuzin and Tribenuron Methyl Herbicides for Controlling Weeds of Various Species in Wheat and Barley Stands. ACS Omega. 2020 Sep 23;5(39):25135-25147. doi: 10.1021/acsomega.0c02492. PMID: 33043192; PMCID: PMC7542591. 5: Yang TT, Zhang HW, Wang J, Li XY, Li X, Su ZC. High bioremediation potential of strain Chenggangzhangella methanolivorans CHL1 for soil polluted with metsulfuron-methyl or tribenuron-methyl in a pot experiment. Environ Sci Pollut Res Int. 2020 Sep 19. doi: 10.1007/s11356-020-10825-w. Epub ahead of print. PMID: 32951166. 6: Hada Z, Khammassi M, Jenfaoui H, Menchari Y, Torra J, Souissi T. Field Survey and Resistance Occurrence to ALS-Inhibiting Herbicides in Glebionis coronaria L. in Tunisian Wheat Crops. Plants (Basel). 2020 Sep 16;9(9):1210. doi: 10.3390/plants9091210. PMID: 32947767; PMCID: PMC7570124. 7: Volova T, Demidenko A, Kurachenko N, Baranovsky S, Petrovskaya O, Shumilova A. Efficacy of embedded metribuzin and tribenuron-methyl herbicides in field- grown vegetable crops infested by weeds. Environ Sci Pollut Res Int. 2020 Aug 22. doi: 10.1007/s11356-020-10359-1. Epub ahead of print. PMID: 32829434. 8: Xu Y, Xu L, Li X, Zheng M. Investigation of resistant level to tribenuron- methyl, diversity and regional difference of the resistant mutations on acetolactate synthase (ALS) isozymes in Descurainia sophia L. from China. Pestic Biochem Physiol. 2020 Oct;169:104653. doi: 10.1016/j.pestbp.2020.104653. Epub 2020 Jul 15. PMID: 32828371. 9: Volova T, Baranovsky S, Petrovskaya O, Shumilova A, Sukovatyi A. Biological effects of the free and embedded metribuzin and tribenuron-methyl herbicides on various cultivated weed species. J Environ Sci Health B. 2020 Aug 20:1-11. doi: 10.1080/03601234.2020.1807835. Epub ahead of print. PMID: 32816605. 10: Gong Q, Dai CY, Zhang XH, Wang XL, Huang Z, Xu AX, Dong JG, Yu CY. Towards breeding of rapeseed (Brassica napus) with alien cytoplasm and powdery mildew resistance from Ethiopian mustard (Brassica carinata). Breed Sci. 2020 Jun;70(3):387-395. doi: 10.1270/jsbbs.20017. Epub 2020 May 19. PMID: 32714062; PMCID: PMC7372030. 11: Maznah Z, Ismail BS, Eng OK. Residue and Dissipation Kinetics of Metsulfuron-Methyl Herbicide in Soil: A Field Assessment at an Oil Palm Plantation. Biomolecules. 2020 Jul 16;10(7):1067. doi: 10.3390/biom10071067. PMID: 32708824; PMCID: PMC7408506. 12: Qi Y, Li J, Guan X, Yan B, Fu G, He J, Du L, Zhao C, Zhang D. Effects of herbicides on non-target plant species diversity and the community composition of fallow fields in northern China. Sci Rep. 2020 Jun 19;10(1):9967. doi: 10.1038/s41598-020-67025-2. PMID: 32561827; PMCID: PMC7305147. 13: Guo Y, Cheng L, Long W, Gao J, Zhang J, Chen S, Pu H, Hu M. Synergistic mutations of two rapeseed AHAS genes confer high resistance to sulfonylurea herbicides for weed control. Theor Appl Genet. 2020 Oct;133(10):2811-2824. doi: 10.1007/s00122-020-03633-w. Epub 2020 Jun 15. PMID: 32556395. 14: Serra-Mora P, Herráez-Hernández R, Campíns-Falcó P. Minimizing the impact of sample preparation on analytical results: In-tube solid-phase microextraction coupled on-line to nano-liquid chromatography for the monitoring of tribenuron methyl in environmental waters. Sci Total Environ. 2020 Jun 15;721:137732. doi: 10.1016/j.scitotenv.2020.137732. Epub 2020 Mar 3. PMID: 32172115. 15: Carpenter DJ, Mathiassen SK, Boutin C, Strandberg B, Casey CS, Damgaard C. Effects of Herbicides on Flowering. Environ Toxicol Chem. 2020 May;39(6):1244-1256. doi: 10.1002/etc.4712. Epub 2020 Apr 29. PMID: 32170767. 16: Huang Q, Lv J, Sun Y, Wang H, Guo Y, Qu G, Hu S. Inheritance and Molecular Characterization of a Novel Mutated AHAS Gene Responsible for the Resistance of AHAS-Inhibiting Herbicides in Rapeseed (Brassica napus L.). Int J Mol Sci. 2020 Feb 17;21(4):1345. doi: 10.3390/ijms21041345. PMID: 32079260; PMCID: PMC7072869. 17: Kiselev EG, Boyandin AN, Zhila NO, Prudnikova SV, Shumilova AA, Baranovskiy SV, Shishatskaya EI, Thomas S, Volova TG. Constructing sustained-release herbicide formulations based on poly-3-hydroxybutyrate and natural materials as a degradable matrix. Pest Manag Sci. 2020 May;76(5):1772-1785. doi: 10.1002/ps.5702. Epub 2019 Dec 25. PMID: 31785186. 18: Ye F, Zhai Y, Guo KL, Liu YX, Li N, Gao S, Zhao LX, Fu Y. Safeners Improve Maize Tolerance under Herbicide Toxicity Stress by Increasing the Activity of Enzymes in Vivo. J Agric Food Chem. 2019 Oct 23;67(42):11568-11576. doi: 10.1021/acs.jafc.9b03587. Epub 2019 Oct 15. PMID: 31584809. 19: Mora DA, Cheimona N, Palma-Bautista C, Rojano-Delgado AM, Osuna-Ruiz MD, Alcántara de la Cruz R, De Prado R. Physiological, biochemical and molecular bases of resistance to tribenuron-methyl and glyphosate in Conyza canadensis from olive groves in southern Spain. Plant Physiol Biochem. 2019 Nov;144:14-21. doi: 10.1016/j.plaphy.2019.09.023. Epub 2019 Sep 18. PMID: 31550609. 20: Li J, Gao X, Li M, Fang F. Resistance evolution and mechanisms to ALS- inhibiting herbicides in Capsella bursa-pastoris populations from China. Pestic Biochem Physiol. 2019 Sep;159:17-21. doi: 10.1016/j.pestbp.2019.05.010. Epub 2019 May 17. PMID: 31400779.