MedKoo Cat#: 574661 | Name: DHPB
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Description:

WARNING: This product is for research use only, not for human or veterinary use.

DHPB is a heptyl viologen that can be used as an electrochromic (EC) material. It forms a highly efficient quenching system for conjugated polyelectrolyte for the development of organic electronics. It also acts as a redox active electrolyte for electrochemical devices (ECDs).

Chemical Structure

DHPB
CAS#6159-05-3

Theoretical Analysis

MedKoo Cat#: 574661

Name: DHPB

CAS#: 6159-05-3

Chemical Formula: C24H38Br2N2

Exact Mass: 0.0000

Molecular Weight: 514.39

Elemental Analysis: C, 56.04; H, 7.45; Br, 31.07; N, 5.45

Price and Availability

Size Price Availability Quantity
1g USD 250.00 2 Weeks
5g USD 550.00 2 Weeks
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Related CAS #
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Synonym
DHPB; Diheptylviologen bromide; Diheptylviologen dibromide; Heptylviologen dibromide;
IUPAC/Chemical Name
1,1′-Diheptyl-4,4′-bipyridinium dibromide
InChi Key
VRXAJMCFEOESJO-UHFFFAOYSA-L
InChi Code
InChI=1S/C24H38N2.2BrH/c1-3-5-7-9-11-17-25-19-13-23(14-20-25)24-15-21-26(22-16-24)18-12-10-8-6-4-2;;/h13-16,19-22H,3-12,17-18H2,1-2H3;2*1H/q+2;;/p-2
SMILES Code
CCCCCCC[N+]1=CC=C(C2=CC=[N+](CCCCCCC)C=C2)C=C1.[Br-].[Br-]
Appearance
Solid powder
Purity
>95% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>3 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 514.39 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1. Quasi-reversible electrochromic behavior of alkyl viologens dispersed mono-molecularly in double-stranded DNA chains Kakibe, T., & Ohno, H. Journal of Materials Chemistry 19(28), 4960-4964, (2009) 2. Ink-Jet Printing of Electron Donor/Acceptor Blends: Towards Bulk Heterojunction Solar Cells Marin, V., Holder, E., Wienk, M. M., Tekin, E., Kozodaev, D., & Schubert, U. S. Macromolecular Rapid Communications 26(4), 319-324, (2005) 3. The effect of ferrocyanide on the performance of heptyl viologen-based electrochromic display devices. Monk PMS. Journal of Electroanalytical Chemistry 432(1-2), 175-179, (1997) 4. Achieving low-energy driven viologens-based electrochromic devices utilizing polymeric ionic liquids. Lu H, et al. ACS Applied Materials & Interfaces 8(44), 30351-30361, (2016) 5. Efficient charge storage in dual-redox electrochemical capacitors through reversible counterion-induced solid complexation. Evanko B, et al. Journal of the American Chemical Society 138(30), 9373-9376, (2016) 6. Effects of polymer aggregation and quencher size on amplified fluorescence quenching of conjugated polyelectrolytes. Jiang H, et al. Langmuir 23(18), 9481-9486, (2007) 7. Electrochemically controllable emission and coloration by using europium (III) complex and viologen derivatives. Nakamura K, et al. Chemical Communications (Cambridge, England) 47(36), 10064-10066, (2011)