MedKoo Cat#: 585270 | Name: Tinopal

Description:

WARNING: This product is for research use only, not for human or veterinary use.

Tinopal is a fluorescent whitening agent and optical brightner used in detergents.

Chemical Structure

Tinopal
CAS#24231-46-7

Theoretical Analysis

MedKoo Cat#: 585270

Name: Tinopal

CAS#: 24231-46-7

Chemical Formula: C40H40N12O8S2

Exact Mass: 880.2533

Molecular Weight: 880.96

Elemental Analysis: C, 54.54; H, 4.58; N, 19.08; O, 14.53; S, 7.28

Price and Availability

This product is currently not in stock but may be available through custom synthesis. To ensure cost efficiency, the minimum order quantity is 1 gram. The estimated lead time is 2 to 4 months, with pricing dependent on the complexity of the synthesis (typically high for intricate chemistries). Quotes for quantities below 1 gram will not be provided. To request a quote, please click the button below. Note: If this product becomes available in stock in the future, pricing will be listed accordingly.
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Related CAS #
No Data
Synonym
Tinopal
IUPAC/Chemical Name
4,4'-Bis((4-anilino-6-morpholino-1,3,5-triazin-2-yl)amino)stilbene-2,2'-disulphonic acid
InChi Key
YGUMVDWOQQJBGA-VAWYXSNFSA-N
InChi Code
InChI=1S/C40H40N12O8S2/c53-61(54,55)33-25-31(43-37-45-35(41-29-7-3-1-4-8-29)47-39(49-37)51-17-21-59-22-18-51)15-13-27(33)11-12-28-14-16-32(26-34(28)62(56,57)58)44-38-46-36(42-30-9-5-2-6-10-30)48-40(50-38)52-19-23-60-24-20-52/h1-16,25-26H,17-24H2,(H,53,54,55)(H,56,57,58)(H2,41,43,45,47,49)(H2,42,44,46,48,50)/b12-11+
SMILES Code
O=S(C1=CC(NC2=NC(NC3=CC=CC=C3)=NC(N4CCOCC4)=N2)=CC=C1/C=C/C5=CC=C(NC6=NC(NC7=CC=CC=C7)=NC(N8CCOCC8)=N6)C=C5S(=O)(O)=O)(O)=O
Appearance
Solid powder
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>3 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 880.96 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1: Ko KY, Lee CA, Choi JC, Kim M. Determination of Tinopal CBS-X in rice papers and rice noodles using HPLC with fluorescence detection and LC-MS/MS. Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2014;31(9):1451-9. doi: 10.1080/19440049.2014.934302. Epub 2014 Aug 19. PubMed PMID: 25035935. 2: Reddy NP, A Khan PA, Devi KU, Victor JS, Sharma HC. Assessment of the suitability of Tinopal as an enhancing adjuvant in formulations of the insect pathogenic fungus Beauveria bassiana (Bals.) Vuillemin. Pest Manag Sci. 2008 Sep;64(9):909-15. doi: 10.1002/ps.1581. PubMed PMID: 18383501. 3: Iamazaki ET, Atvars TD. Role of surfactants in the sorption of the whitening agent Tinopal CBS onto viscose fibers: a fluorescence spectroscopy study. Langmuir. 2006 Nov 21;22(24):9866-73. PubMed PMID: 17106975. 4: Iamazaki ET, Atvars TD. Sorption of a fluorescent whitening agent (Tinopal CBS) onto modified cellulose fibers in the presence of surfactants and salt. Langmuir. 2007 Dec 18;23(26):12886-92. Epub 2007 Nov 17. PubMed PMID: 18020381. 5: Murillo R, Lasa R, Goulson D, Williams T, Muñoz D, Caballero P. Effect of tinopal LPW on the insecticidal properties and genetic stability of the nucleopolyhedrovirus of Spodoptera exigua (Lepidoptera: Noctuidae). J Econ Entomol. 2003 Dec;96(6):1668-74. PubMed PMID: 14977102. 6: Black JG, Moule RC, Philp J. Percutaneous absorption and disposition of Tinopal EMS. Toxicology. 1977 Aug;8(1):33-42. PubMed PMID: 929616. 7: Nickle WR, Shapiro M. Use of a Stilbene Brightener, Tinopal LPW, as a Radiation Protectant for Steinernema carpocapsae. J Nematol. 1992 Sep;24(3):371-3. PubMed PMID: 19283011; PubMed Central PMCID: PMC2619288. 8: Mondragón G, Pineda S, Martínez A, Martínez AM. Optical brightener Tinopal C1101 as an ultraviolet protectant for a nucleopolyhedrovirus. Commun Agric Appl Biol Sci. 2007;72(3):543-7. PubMed PMID: 18399486. 9: Yamaki SB, Barros DS, Garcia CM, Socoloski P, Oliveira ON Jr, Atvars TD. Spectroscopic studies of the intermolecular interactions of Congo red and tinopal CBS with modified cellulose fibers. Langmuir. 2005 Jun 7;21(12):5414-20. PubMed PMID: 15924470. 10: Arakawa T, Kamimura M, Furuta Y, Miyazawa M, Kato M. Peroral infection of nuclear polyhedrosis virus budded particles in the host, Bombyx mori l., enabled by an optical brightener, Tinopal UNPA-GX. J Virol Methods. 2000 Aug;88(2):145-52. PubMed PMID: 10960702. 11: Bernal A, Simón O, Williams T, Caballero P. Stage-specific insecticidal characteristics of a nucleopolyhedrovirus isolate from Chrysodeixis chalcites enhanced by optical brighteners. Pest Manag Sci. 2014 May;70(5):798-804. doi: 10.1002/ps.3617. Epub 2013 Aug 22. PubMed PMID: 23893929. 12: Phillips MK, Kell DB, Rhodes-Roberts ME. The antibacterial action of Tinopal AN. J Gen Microbiol. 1984 Aug;130(8):1999-2005. PubMed PMID: 6206200. 13: Mohite BV, Patil SV. Investigation of Bacterial Cellulose Biosynthesis Mechanism in Gluconoacetobacter hansenii. ISRN Microbiol. 2014 Mar 16;2014:836083. doi: 10.1155/2014/836083. eCollection 2014. PubMed PMID: 25031880; PubMed Central PMCID: PMC3976816. 14: Phatangare KR, Lanke SK, Sekar N. Phenalenone fluorophores-synthesis, photophysical properties and DFT study. J Fluoresc. 2014 Nov;24(6):1827-40. doi: 10.1007/s10895-014-1471-3. Epub 2014 Oct 5. PubMed PMID: 25284713. 15: Shapiro M, Argauer R. Relative effectiveness of selected stilbene optical brighteners as enhancers of the beet armyworm (Lepidoptera: Noctuidae) nuclear polyhedrosis virus. J Econ Entomol. 2001 Apr;94(2):339-43. PubMed PMID: 11332823. 16: Martínez AM, Velasco S, Méndez A, Figueroa JI, España ML, Cárdenas-Navarro R, Pineda S. Effects of optical brighteners used in biopesticide formulations on crops: reflectance, stomatal conductance, photosynthesis, and growth. Commun Agric Appl Biol Sci. 2009;74(1):117-23. PubMed PMID: 20218517. 17: Mukawa S, Goto C. Enhancement of nucleopolyhedrovirus infectivity against Mamestra brassicae (Lepidoptera: Noctuidae) by proteins derived from granulovirus and a fluorescent brightener. J Econ Entomol. 2007 Aug;100(4):1075-83. PubMed PMID: 17849854. 18: Mukawa S, Goto C. In vivo characterization of a group II nucleopolyhedrovirus isolated from Mamestra brassicae (Lepidoptera: Noctuidae) in Japan. J Gen Virol. 2006 Jun;87(Pt 6):1491-500. PubMed PMID: 16690913. 19: Matuszek DB, Wojtkiewicz K. Assessment of the Content of Fluorescent Tracer in Granular Feed Mixture. J AOAC Int. 2018 Nov 1;101(6):1752-1756. doi: 10.5740/jaoacint.17-0114. Epub 2018 May 3. PubMed PMID: 29724264. 20: Martínez AM, Williams T, López-Ferber M, Caballero P. Optical brighteners do not influence covert baculovirus infection of Spodoptera frugiperda. Appl Environ Microbiol. 2005 Mar;71(3):1668-70. PubMed PMID: 15746377; PubMed Central PMCID: PMC1065160.