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MedKoo Cat#: 581372 | Name: Tribufos

Description:

WARNING: This product is for research use only, not for human or veterinary use.

Tribufos is used in pesticide formulations and is classified as an insect growth regulator (1,2). Drinking water contaminant candidate list 3 (CCL 3) compound as per United States Environmental Protection Agency (EPA), environmental, and food contaminants.

Chemical Structure

Tribufos
Tribufos
CAS#78-48-8

Theoretical Analysis

MedKoo Cat#: 581372

Name: Tribufos

CAS#: 78-48-8

Chemical Formula: C12H27OPS3

Exact Mass: 314.0962

Molecular Weight: 314.50

Elemental Analysis: C, 45.83; H, 8.65; O, 5.09; P, 9.85; S, 30.58

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Synonym
Tribufos; Fossfall; Butiphos; Tribuphos;
IUPAC/Chemical Name
Phosphorotrithioic acid, S,S,S-tributyl ester
InChi Key
ZOKXUAHZSKEQSS-UHFFFAOYSA-N
InChi Code
InChI=1S/C12H27OPS3/c1-4-7-10-15-14(13,16-11-8-5-2)17-12-9-6-3/h4-12H2,1-3H3
SMILES Code
O=P(SCCCC)(SCCCC)SCCCC
Appearance
liquid
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>3 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.03.00
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 314.50 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
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Pestic Biochem Physiol. 2016 Oct;133:91-96. doi: 10.1016/j.pestbp.2016.02.007. Epub 2016 Feb 23. PubMed PMID: 27742367. 5: Queiroz MC, Sato ME. Pyrethroid resistance in Phytoseiulus macropilis (Acari: Phytoseiidae): cross-resistance, stability and effect of synergists. Exp Appl Acarol. 2016 Jan;68(1):71-82. doi: 10.1007/s10493-015-9984-2. Epub 2015 Nov 3. PubMed PMID: 26530989. 6: Afzal MB, Shad SA, Abbas N. Genetics, realized heritability and preliminary mechanism of spinosad resistance in Phenacoccus solenopsis Tinsley (Homoptera: Pseudococcidae): an invasive pest from Pakistan. Genetica. 2015 Dec;143(6):741-9. doi: 10.1007/s10709-015-9871-0. Epub 2015 Oct 22. PubMed PMID: 26494239. 7: Demkovich M, Siegel JP, Higbee BS, Berenbaum MR. Mechanism of Resistance Acquisition and Potential Associated Fitness Costs in Amyelois transitella (Lepidoptera: Pyralidae) Exposed to Pyrethroid Insecticides. Environ Entomol. 2015 Jun;44(3):855-63. doi: 10.1093/ee/nvv047. Epub 2015 Apr 22. PubMed PMID: 26313992. 8: Afzal MB, Ijaz M, Farooq Z, Shad SA, Abbas N. Genetics and preliminary mechanism of chlorpyrifos resistance in Phenacoccus solenopsis Tinsley (Homoptera: Pseudococcidae). Pestic Biochem Physiol. 2015 Mar;119:42-7. doi: 10.1016/j.pestbp.2015.02.008. Epub 2015 Feb 27. PubMed PMID: 25868815. 9: Bao WX, Narai Y, Nakano A, Kaneda T, Murai T, Sonoda S. Spinosad resistance of melon thrips, Thrips palmi, is conferred by G275E mutation in α6 subunit of nicotinic acetylcholine receptor and cytochrome P450 detoxification. Pestic Biochem Physiol. 2014 Jun;112:51-5. doi: 10.1016/j.pestbp.2014.04.013. Epub 2014 May 9. PubMed PMID: 24974117. 10: He Y, Zhang J, Chen J. Effect of synergists on susceptibility to chlorantraniliprole in field populations of Chilo suppressalis (Lepidoptera: Pyralidae). J Econ Entomol. 2014 Apr;107(2):791-6. PubMed PMID: 24772562. 11: Lopatina IuV, Eremina OIu, Iakovlev ÉA. [Pyrethroid resistance mechanisms in the body lice Pediculus humanus humanus L.: detoxification enzyme systems]. Med Parazitol (Mosk). 2014 Jan-Mar;(1):19-24. Russian. PubMed PMID: 24738222. 12: Abbas N, Khan HA, Shad SA. Cross-resistance, genetics, and realized heritability of resistance to fipronil in the house fly, Musca domestica (Diptera: Muscidae): a potential vector for disease transmission. Parasitol Res. 2014 Apr;113(4):1343-52. doi: 10.1007/s00436-014-3773-4. Epub 2014 Jan 31. PubMed PMID: 24481906. 13: Ang LH, Nazni WA, Kuah MK, Shu-Chien AC, Lee CY. Detection of the A302S Rdl mutation in fipronil bait-selected strains of the German cockroach (Dictyoptera: Blattellidae). J Econ Entomol. 2013 Oct;106(5):2167-76. Erratum in: J Econ Entomol. 2013 Dec;106(6):v. PubMed PMID: 24224261. 14: Grisales N, Poupardin R, Gomez S, Fonseca-Gonzalez I, Ranson H, Lenhart A. Temephos resistance in Aedes aegypti in Colombia compromises dengue vector control. PLoS Negl Trop Dis. 2013 Sep 19;7(9):e2438. doi: 10.1371/journal.pntd.0002438. eCollection 2013. PubMed PMID: 24069492; PubMed Central PMCID: PMC3777894. 15: Anderson TA, Salice CJ, Erickson RA, McMurry ST, Cox SB, Smith LM. Effects of landuse and precipitation on pesticides and water quality in playa lakes of the southern high plains. Chemosphere. 2013 Jun;92(1):84-90. doi: 10.1016/j.chemosphere.2013.02.054. Epub 2013 Mar 29. PubMed PMID: 23541358. 16: Couso-Ferrer F, Arouri R, Beroiz B, Perera N, Cervera A, Navarro-Llopis V, Castañera P, Hernández-Crespo P, Ortegoa F. Cross-resistance to insecticides in a malathion-resistant strain of Ceratitis capitata (Diptera: Tephritidae). J Econ Entomol. 2011 Aug;104(4):1349-56. PubMed PMID: 21882703. 17: López-Soler N, Cervera A, Quinto V, Abellán J, Bielza P, Martínez-Pardo R, Garcerá MD. Esterase inhibition by synergists in the western flower thrips Frankliniella occidentalis. Pest Manag Sci. 2011 Dec;67(12):1549-56. doi: 10.1002/ps.2211. Epub 2011 Jun 8. PubMed PMID: 21656898. 18: Shi J, Zhang L, Gao X. Characterisation of spinosad resistance in the housefly Musca domestica (Diptera: Muscidae). Pest Manag Sci. 2011 Mar;67(3):335-40. doi: 10.1002/ps.2073. Epub 2011 Jan 11. PubMed PMID: 21308959. 19: Brausch KA, Anderson TA, Smith PN, Maul JD. Effects of functionalized fullerenes on bifenthrin and tribufos toxicity to Daphnia magna: Survival, reproduction, and growth rate. Environ Toxicol Chem. 2010 Nov;29(11):2600-6. doi: 10.1002/etc.318. PubMed PMID: 20853424. 20: Matowo J, Kulkarni MA, Mosha FW, Oxborough RM, Kitau JA, Tenu F, Rowland M. Biochemical basis of permethrin resistance in Anopheles arabiensis from Lower Moshi, north-eastern Tanzania. Malar J. 2010 Jul 7;9:193. doi: 10.1186/1475-2875-9-193. PubMed PMID: 20609220; PubMed Central PMCID: PMC3224900.