Anilofos | CAS#64249-01-0 | herbicide

MedKoo Cat#: 461321 | Name: Anilofos

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Description:

WARNING: This product is for research use only, not for human or veterinary use.

Anilofos is a widely used thionoorganophosphate herbicide. It is used for pre-emergence and early post-emergence control annual grass weeds and sedges in transplanted rice crops.

Chemical Structure

Anilofos

CAS#64249-01-0

Theoretical Analysis

MedKoo Cat#: 461321

Name: Anilofos

CAS#: 64249-01-0

Chemical Formula: C13H19ClNO3PS2

Exact Mass: 367.0232

Molecular Weight: 367.84

Elemental Analysis: C, 42.45; H, 5.21; Cl, 9.64; N, 3.81; O, 13.05; P, 8.42; S, 17.43

Price and Availability

Size	Price	Availability	Quantity
100mg	USD 350.00	2 Weeks

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Related CAS #

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Synonym

Anilofos; Arozin; Rico;

IUPAC/Chemical Name

S-(2-((4-chlorophenyl)(isopropyl)amino)-2-oxoethyl) O,O-dimethyl phosphorodithioate

InChi Key

NXQDBZGWYSEGFL-UHFFFAOYSA-N

InChi Code

InChI=1S/C13H19ClNO3PS2/c1-10(2)15(12-7-5-11(14)6-8-12)13(16)9-21-19(20,17-3)18-4/h5-8,10H,9H2,1-4H3

SMILES Code

S=P(OC)(SCC(N(C1=CC=C(Cl)C=C1)C(C)C)=O)OC

Appearance

Solid powder

Purity

>98% (or refer to the Certificate of Analysis)

Shipping Condition

Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition

Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).

Solubility

Soluble in DMSO

Shelf Life

>3 years if stored properly

Drug Formulation

This drug may be formulated in DMSO

Stock Solution Storage

0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code

2934.99.03.00

More Info

Instruction

View handling instruction

Preparing Stock Solutions

The following data is based on the product molecular weight 367.84 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Concentration / Solvent Volume / Mass	1 mg	5 mg	10 mg
1 mM	1.15 mL	5.76 mL	11.51 mL
5 mM	0.23 mL	1.15 mL	2.3 mL
10 mM	0.12 mL	0.58 mL	1.15 mL
50 mM	0.02 mL	0.12 mL	0.23 mL

1: Singh DP, Khattar JI, Kaur M, Kaur G, Gupta M, Singh Y. Anilofos tolerance and its mineralization by the cyanobacterium Synechocystis sp. strain PUPCCC 64. PLoS One. 2013;8(1):e53445. doi: 10.1371/journal.pone.0053445. Epub 2013 Jan 31. PMID: 23382844; PMCID: PMC3561370. 2: Bagri P, Kumar V. Assessment of anilofos-induced mutagenicity in bone marrow and germ cells of Swiss albino mice. Toxicol Ind Health. 2020 Feb;36(2):110-118. doi: 10.1177/0748233720913757. PMID: 32279653. 3: Özkara A, Akyıl D, Eren Y, Erdoğmuş SF. Potential cytotoxic effect of Anilofos by using Allium cepa assay. Cytotechnology. 2015 Oct;67(5):783-91. doi: 10.1007/s10616-014-9716-1. Epub 2014 May 17. PMID: 24838422; PMCID: PMC4545445. 4: Akyil D, Konuk M, Eren Y, Liman R, Sağlam E. Mutagenic and genotoxic effects of Anilofos with micronucleus, chromosome aberrations, sister chromatid exchanges and Ames test. Cytotechnology. 2017 Dec;69(6):865-874. doi: 10.1007/s10616-017-0099-y. Epub 2017 Jun 12. PMID: 28608257; PMCID: PMC5660744. 5: Tandon S. Degradation kinetics of anilofos in soil and residues in rice crop at harvest. Pest Manag Sci. 2014 Nov;70(11):1706-10. doi: 10.1002/ps.3707. Epub 2014 Feb 17. PMID: 24339403. 6: Hazarika A, Sarkar SN. Effect of isoproturon pretreatment on the biochemical toxicodynamics of anilofos in male rats. Toxicology. 2001 Aug 28;165(2-3):87-95. doi: 10.1016/s0300-483x(01)00411-5. PMID: 11522367. 7: Aggarwal M, Wangikar PB, Sarkar SN, Rao GS, Kumar D, Dwivedi P, Malik JK. Effects of low-level arsenic exposure on the developmental toxicity of anilofos in rats. J Appl Toxicol. 2007 May-Jun;27(3):255-61. doi: 10.1002/jat.1203. PMID: 17304642. 8: Hazarika A, Sarkar SN, Hajare S, Kataria M, Malik JK. Influence of malathion pretreatment on the toxicity of anilofos in male rats: a biochemical interaction study. Toxicology. 2003 Mar 14;185(1-2):1-8. doi: 10.1016/s0300-483x(02)00574-7. PMID: 12505439. 9: Zhang Y, Gao AH, Liu B, Sheng W, Tan C, Yuan M, Wang S. A direct competitive enzyme-linked immunosorbent assay for rapid detection of anilofos residues in agricultural products and environmental samples. J Environ Sci Health B. 2013;48(1):1-8. doi: 10.1080/03601234.2012.716667. PMID: 23030434. 10: Hazarika A, Sarkar SN. Subacute toxicity of anilofos, a new organophosphorus herbicide, in male rats: effect on some physical attributes and acetylcholinesterase activity. Indian J Exp Biol. 2001 Nov;39(11):1107-12. PMID: 11906102. 11: Zhang J, Zheng JW, Hang BJ, Ni YY, He J, Li SP. Rhodanobacter xiangquanii sp. nov., a novel anilofos-degrading bacterium isolated from a wastewater treating system. Curr Microbiol. 2011 Feb;62(2):645-9. doi: 10.1007/s00284-010-9757-4. Epub 2010 Oct 10. PMID: 20936473. 12: Hazarika A, Sarkar SN, Kataria M. Subacute toxicity of anilofos, a new organophosphorus herbicide in male rats: effect on lipid peroxidation and ATPase activity. Indian J Exp Biol. 2001 Nov;39(11):1113-7. PMID: 11906103. 13: Singh SB, Kulshrestha G. Identification of impurities in technical anilofos and their effect on transplanted rice. J Agric Food Chem. 2001 Aug;49(8):3728-35. doi: 10.1021/jf010062o. PMID: 11513656. 14: Pehar V, Kolić D, Zandona A, Šinko G, Katalinić M, Stepanić V, Kovarik Z. Selected herbicides screened for toxicity and analysed as inhibitors of both cholinesterases. Chem Biol Interact. 2023 Jul 1;379:110506. doi: 10.1016/j.cbi.2023.110506. Epub 2023 May 2. PMID: 37141932. 15: Tantawy AA. Molluscicidal effect of fenitrothion and anilofos on Lymnaea natalensis and Biomphalaria alexandrina snails and on the free larval stages of Schistosoma mansoni. J Egypt Soc Parasitol. 2006 Aug;36(2):629-42. PMID: 16927873. 16: Zidan ZH, Ragab FM, Mohamed KH. Molluscicidal activities of certain pesticide and their mixtures against Biomphalaria alexandrina. J Egypt Soc Parasitol. 2002 Apr;32(1):285-96. PMID: 12049263. 17: Tsuda T, Nakamura T, Inoue A, Tanaka K. Pesticides in water, fish and shellfish from littoral area of Lake Biwa. Bull Environ Contam Toxicol. 2009 Jun;82(6):716-21. doi: 10.1007/s00128-009-9681-0. Epub 2009 Mar 10. PMID: 19277442. 18: Bakry FA, Sakrane AA, Ismail NM. Molluscicidal effect of fungicide, herbicide and plant extract on some biological and physiological parameters of Biomphalaria alexandrina. J Egypt Soc Parasitol. 2002 Dec;32(3):821-35. PMID: 12512815. 19: Patnaik GK, Kanungo PK, Moorthy BT, Mahana PK, Adhya TK, Rao VR. Effect of herbicides on nitrogen fixation (C2H2 reduction) associated with rice rhizosphere. Chemosphere. 1995 Jan;30(2):339-43. doi: 10.1016/0045-6535(94)00401-f. PMID: 7874477.