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MedKoo Cat#: 596286 | Name: Chinomethionat

Description:

WARNING: This product is for research use only, not for human or veterinary use.

Chinomethionat is an acaricide, insecticide and fungicide.

Chemical Structure

Chinomethionat
Chinomethionat
CAS#2439-01-2

Theoretical Analysis

MedKoo Cat#: 596286

Name: Chinomethionat

CAS#: 2439-01-2

Chemical Formula: C10H6N2OS2

Exact Mass: 233.9922

Molecular Weight: 234.29

Elemental Analysis: C, 51.27; H, 2.58; N, 11.96; O, 6.83; S, 27.37

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Synonym
Chinomethionat; NSC 379587; NSC-379587; NSC379587; Chinomethionate; Oxythioquinox; QUINOMETHIONATE
IUPAC/Chemical Name
6-methyl-[1,3]dithiolo[4,5-b]quinoxalin-2-one
InChi Key
FBQQHUGEACOBDN-UHFFFAOYSA-N
InChi Code
InChI=1S/C10H6N2OS2/c1-5-2-3-6-7(4-5)12-9-8(11-6)14-10(13)15-9/h2-4H,1H3
SMILES Code
O=C1SC2=NC3=CC=C(C)C=C3N=C2S1
Appearance
Solid powder
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>2 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 234.29 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1: Sasaki K, Tatsuno T, Nakamura M, Anazawa A, Imazawa T, Utsunomiya O, Ohshima T, Osada H, Kaneko M, Toyoda M. [Method-performance studies of notified analytical method for chinomethionat]. Shokuhin Eiseigaku Zasshi. 2001 Aug;42(4):273-7. Japanese. doi: 10.3358/shokueishi.42.273. PMID: 11817145. 2: Nemoto S, Takatsuki S, Sasaki K, Toyoda M. [Studies on the stability of 89 pesticides in organic solvent]. Kokuritsu Iyakuhin Shokuhin Eisei Kenkyusho Hokoku. 1997;(115):86-92. Japanese. PMID: 9641820. 3: Stensvand A, Christiansen A. Investigation on fungicide residues in greenhouse-grown strawberries. J Agric Food Chem. 2000 Mar;48(3):917-20. doi: 10.1021/jf990418k. PMID: 10725174. 4: Cabral R, Hoshiya T, Hakoi K, Hasegawa R, Fukushima S, Ito N. A rapid in vivo bioassay for the carcinogenicity of pesticides. Tumori. 1991 Jun 30;77(3):185-8. doi: 10.1177/030089169107700301. PMID: 1862543. 5: Yoon S, Tanaka H. Formation of N-nitrosamines by chloramination or ozonation of amines listed in Pollutant Release and Transfer Registers (PRTRs). Chemosphere. 2014 Jan;95:88-95. doi: 10.1016/j.chemosphere.2013.07.090. Epub 2013 Sep 5. PMID: 24011895. 6: Yamano T, Morita S. Effects of pesticides on isolated rat hepatocytes, mitochondria, and microsomes. Arch Environ Contam Toxicol. 1993 Aug;25(2):271-8. doi: 10.1007/BF00212141. PMID: 8368870. 7: Carrera G, Cambon-Gros C, Mitjavila S. Oxythioquinox-induced hepatomegaly. Toxicol Lett. 1983 Oct-Nov;19(1-2):159-64. doi: 10.1016/0378-4274(83)90277-1. PMID: 6658821. 8: Qi J, Li T, Chan AS. Fungicide chinomethionate as a new family of photoinducible DNA-cleaving agents. Bioorg Med Chem Lett. 2003 Oct 20;13(20):3561-3. doi: 10.1016/s0960-894x(03)00745-5. PMID: 14505671. 9: Gwinn MR, Weston A. Application of oligonucleotide microarray technology to toxic occupational exposures. J Toxicol Environ Health A. 2008;71(5):315-24. doi: 10.1080/15287390701738509. PMID: 18214805. 10: Dent MP. Strengths and limitations of using repeat-dose toxicity studies to predict effects on fertility. Regul Toxicol Pharmacol. 2007 Aug;48(3):241-58. doi: 10.1016/j.yrtph.2007.04.001. Epub 2007 Apr 12. PMID: 17512650. 11: Kitajima EW, Rezende JA, Rodrigues JC. Passion fruit green spot virus vectored by Brevipalpus phoenicis (Acari: Tenuipalpidae) on passion fruit in Brazil. Exp Appl Acarol. 2003;30(1-3):225-31. doi: 10.1023/b:appa.0000006551.74604.84. PMID: 14756419. 12: Gwinn MR, Whipkey DL, Weston A. The effect of oxythioquinox exposure on normal human mammary epithelial cell gene expression: a microarray analysis study. Environ Health. 2004 Sep 23;3(1):9. doi: 10.1186/1476-069X-3-9. PMID: 15387888; PMCID: PMC521696. 13: Carrera G, Mitjavila S, Delvolve N, Derache R. Influence du taux de calories lipidiques de la ration alimentaire sur les effets nutritionnels de l'oxythioquinox chez le rat [Influence of the amount of lipid calories in the diet on the nutritional effects of oxythioquinox in the rat]. Nutr Metab. 1980;24(2):76-90. French. PMID: 7443092. 14: Gaillard D, Chamoiseau G, Derache R. Effect of morestan and other substituted quinoxalines on the activities of various rat hepatic mixed-function oxidases. Arch Environ Contam Toxicol. 1977;5(4):403-13. doi: 10.1007/BF02220920. PMID: 883849. 15: Carrera G, Mitjavila S, Luong-Dinh C, Derache R. Effets nutritionnels, chez le rat, de l'oxythioquinox (morestan), en fonction de sa concentration et du taux de lipides du régime [Nutritional effects in the rat of oxythioquinox (morestan) as a function of its concentration and of the lipid content of the diet]. Ann Nutr Aliment. 1976;30(1):55-65. French. PMID: 1015740. 16: Carrera G, Mitjavila S, Derache R. Toxicity of oxythioquinox in relation to the fat content of the diet: study of the metabolic activity of rat intestinal epithelium. Toxicol Eur Res. 1979 Jul;2(4):187-93. PMID: 161935. 17: Carrera G, Mitjavila S, Derache R. Hypertrophie du foie provoquée par l'oxythioquinox: influence du traux de lipides de la ration alimentaire [Liver enlargement induced by oxythioquinox: effect of the fat content of the diet (author's transl)]. Experientia. 1979 May 15;35(5):648-50. French. doi: 10.1007/BF01960377. PMID: 446669. 18: Krause RT, August EM. Applicability of a multiresidue method and high performance liquid chromatography for determining quinomethionate in apples and oranges. J Assoc Off Anal Chem. 1983 Jul;66(4):1018-22. PMID: 6885686. 19: Gaillard D, Chamoiseau G, Derache R. Dietary effects on inhibition of rat hepatic microsomal drug-metabolizing enzymes by a pesticide (Morestan). Toxicology. 1977 Aug;8(1):23-32. doi: 10.1016/0300-483x(77)90020-8. PMID: 929614. 20: Francoeur Y, Mallet V. Determination of quinomethionate (6-methylquinoline-2,3-diyldithiocarbonate) residues in crops by in situ fluorometry. J Assoc Off Anal Chem. 1976 Jan;59(1):172-3. PMID: 1249034.