Synonym
Fensulfothion; Dasanit; Daconit; Terracur P;
IUPAC/Chemical Name
Phosphorothioic acid, O,O-diethyl O-(4-(methylsulfinyl)phenyl) ester
InChi Key
XDNBJTQLKCIJBV-UHFFFAOYSA-N
InChi Code
InChI=1S/C11H17O4PS2/c1-4-13-16(17,14-5-2)15-10-6-8-11(9-7-10)18(3)12/h6-9H,4-5H2,1-3H3
SMILES Code
S=P(OCC)(OC1=CC=C(S(C)=O)C=C1)OCC
Appearance
Oily yellow or brown liquid
Purity
>95% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>2 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
Preparing Stock Solutions
The following data is based on the
product
molecular weight
308.35
Batch specific molecular weights may vary
from batch to batch
due to the degree of hydration, which will
affect the solvent
volumes required to prepare stock solutions.
| Concentration / Solvent Volume / Mass |
1 mg |
5 mg |
10 mg |
| 1 mM |
1.15 mL |
5.76 mL |
11.51 mL |
| 5 mM |
0.23 mL |
1.15 mL |
2.3 mL |
| 10 mM |
0.12 mL |
0.58 mL |
1.15 mL |
| 50 mM |
0.02 mL |
0.12 mL |
0.23 mL |
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2: Sugitate K, Yamagami T, Nakamura S, Toriba A, Hayakawa K. Deoxidation of fenthion sulfoxide, fenthion oxon sulfoxide and fensulfothion in gas chromatograph/mass spectrometer, and the prevention of sulfoxide deoxidation by polyethylene glycol 300. Anal Sci. 2012;28(7):669-73. PubMed PMID: 22790368.
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4: Elliott JE, Langelier KM, Mineau P, Wilson LK. Poisoning of bald eagles and red-tailed hawks by carbofuran and fensulfothion in the Fraser Delta of British Columbia, Canada. J Wildl Dis. 1996 Jul;32(3):486-91. PubMed PMID: 8827674.
5: Mac Rae IC, Cameron AJ. Bacterial reduction of fensulfothion and its hydrolysis product 4-methylsulfinyl phenol. Appl Environ Microbiol. 1985 Jan;49(1):236-7. PubMed PMID: 3156557; PubMed Central PMCID: PMC238378.
6: Sheela S, Pai SB. Metabolism of fensulfothion by a soil bacterium, Pseudomonas alcaligenes C1. Appl Environ Microbiol. 1983 Aug;46(2):475-9. PubMed PMID: 6226243; PubMed Central PMCID: PMC239414.
7: Greenhalgh R, Read DC. Persistence of fensulfothion in a sandy-loam soil and uptake by rutabagas, carrots and radishes using microplots. J Environ Sci Health B. 1981;16(3):363-79. PubMed PMID: 6454720.
8: Timms P, MacRae IC. Conversion of fensulfothion by Klebsiella pneumoniae to fensulfothion sulfide and its accumulation. Aust J Biol Sci. 1982;35(6):661-7. PubMed PMID: 6220691.
9: Stein ER, Heald CM, Murray AT. Residues of fensulfothion in selected vegetable crops. J Agric Food Chem. 1980 Jan-Feb;28(1):164-7. PubMed PMID: 6444643.
10: Williams IH, Brown MJ, Finlayson DG. Determination of residues of fensulfothion and its sulfone in muck soil. J Agric Food Chem. 1972 Nov-Dec;20(6):1219-21. PubMed PMID: 4263697.
11: Miles JR, Moy P. Degradation of the insecticide fensulfothion by a mixed culture of soil microorganisms. J Environ Sci Health B. 1982;17(6):675-81. PubMed PMID: 6220051.
12: Wood PA, MacRae IC. Reduction of fensulfothion to fensulfothion sulfide by Klebsiella pneumoniae. Appl Environ Microbiol. 1977 Sep;34(3):247-50. PubMed PMID: 143907; PubMed Central PMCID: PMC242637.
13: Miles JR, Bowman BT, Harris CR. Adsorption, desorption, soil mobility and aqueous persistence of fensulfothion and its sulfide and sulfone metabolites. J Environ Sci Health B. 1981;16(3):309-24. PubMed PMID: 6454719.
14: Timms P, MacRae IC. Reduction of fensulfothion and accumulation of the product, fensulfothion sulfide, by selected microbes. Bull Environ Contam Toxicol. 1983 Jul;31(1):112-5. PubMed PMID: 6224524.
15: Zhang Q, Wang C. Toxicity of binary mixtures of enantiomers in chiral organophosphorus insecticides: the significance of joint effects between enantiomers. Chirality. 2013 Nov;25(11):787-92. doi: 10.1002/chir.22215. Epub 2013 Jul 29. PubMed PMID: 23893823.
16: Hiblot J, Gotthard G, Chabriere E, Elias M. Characterisation of the organophosphate hydrolase catalytic activity of SsoPox. Sci Rep. 2012;2:779. doi: 10.1038/srep00779. Epub 2012 Nov 8. PubMed PMID: 23139857; PubMed Central PMCID: PMC3493116.
17: George DA. Determination of residues of fensulfothion and its metabolites in Chinese cabbage, Japanese radish , and turnips. J Assoc Off Anal Chem. 1980 Sep;63(5):1109-13. PubMed PMID: 6447687.
18: Lucas LT. Population Dynamics of Belonolaimus longicaudatus and Criconemella ornata and Growth Response of Bermudagrass and Overseeded Grasses on Golf Greens Following Treatment with Nematicides. J Nematol. 1982 Jul;14(3):358-63. PubMed PMID: 19295721; PubMed Central PMCID: PMC2618188.
19: González-Curbelo MÁ, Hernández-Borges J, Borges-Miquel TM, Rodríguez-Delgado MÁ. Determination of pesticides and their metabolites in processed cereal samples. Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2012;29(1):104-16. doi: 10.1080/19440049.2011.615032. Epub 2011 Nov 1. PubMed PMID: 22043870.
20: Fleming WJ, Bradbury SP. Recovery of cholinesterase activity in mallard ducklings administered organophosphorus pesticides. J Toxicol Environ Health. 1981 Nov-Dec;8(5-6):885-97. PubMed PMID: 7338949.
