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MedKoo Cat#: 571464 | Name: Bromopropylate

Description:

WARNING: This product is for research use only, not for human or veterinary use.

Bromopropylate is an insecticide that is the active substance in fumigant strips for mites.

Chemical Structure

Bromopropylate
Bromopropylate
CAS#18181-80-1

Theoretical Analysis

MedKoo Cat#: 571464

Name: Bromopropylate

CAS#: 18181-80-1

Chemical Formula: C17H16Br2O3

Exact Mass: 425.9466

Molecular Weight: 428.12

Elemental Analysis: C, 47.69; H, 3.77; Br, 37.33; O, 11.21

Price and Availability

Size Price Availability Quantity
250mg USD 188.00
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Related CAS #
No Data
Synonym
Bromopropylate; Acarol
IUPAC/Chemical Name
Benzeneacetic acid, 4-bromo-alpha-(4-bromophenyl)-alpha-hydroxy-, 1-methylethyl ester
InChi Key
FOANIXZHAMJWOI-UHFFFAOYSA-N
InChi Code
InChI=1S/C17H16Br2O3/c1-11(2)22-16(20)17(21,12-3-7-14(18)8-4-12)13-5-9-15(19)10-6-13/h3-11,21H,1-2H3
SMILES Code
O=C(OC(C)C)C(O)(C1=CC=C(Br)C=C1)C2=CC=C(Br)C=C2
Appearance
Solid powder
Purity
>98% (or refer to the Certificate of Analysis)
Shipping Condition
Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.
Storage Condition
Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).
Solubility
Soluble in DMSO
Shelf Life
>2 years if stored properly
Drug Formulation
This drug may be formulated in DMSO
Stock Solution Storage
0 - 4 C for short term (days to weeks), or -20 C for long term (months).
HS Tariff Code
2934.99.9001
More Info

Preparing Stock Solutions

The following data is based on the product molecular weight 428.12 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Recalculate based on batch purity %
Concentration / Solvent Volume / Mass 1 mg 5 mg 10 mg
1 mM 1.15 mL 5.76 mL 11.51 mL
5 mM 0.23 mL 1.15 mL 2.3 mL
10 mM 0.12 mL 0.58 mL 1.15 mL
50 mM 0.02 mL 0.12 mL 0.23 mL
1: Zhang Q, Liu C, Wu N, Wu X, Li S. [Determination of propargite, tebuconazole and bromopropylate pesticide residues in Taiwan green jujubes by gas chromatography-tandem mass spectrometry]. Se Pu. 2014 Aug;32(8):886-9. Chinese. PubMed PMID: 25434127. 2: Kostka G, Kopeć-Szlezak J, Palut D. Early hepatic changes induced in rats by two hepatocarcinogenic organohalogen pesticides: bromopropylate and DDT. Carcinogenesis. 1996 Mar;17(3):407-12. PubMed PMID: 8631124. 3: Barba A, Camara MA, Navarro Garcia S, Sanchez-Fresneda C, Lopez de Hierro N, Acebes A. Disappearance of bromopropylate residues in artichokes, strawberries and beans. J Environ Sci Health B. 1991 Jun;26(3):323-32. PubMed PMID: 1894918. 4: Ramón-Azcón J, Sánchez-Baeza F, Sanvicens N, Marco MP. Development of an enzyme-linked immunosorbent assay for determination of the miticide bromopropylate. J Agric Food Chem. 2009 Jan 28;57(2):375-84. doi: 10.1021/jf802821n. PubMed PMID: 19113903. 5: Thomas H, Sagelsdorff P, Molitor E, Skripsky T, Waechter F. Bromopropylate: induction of hepatic cytochromes P450 and absence of covalent binding to DNA in mouse liver. Toxicol Appl Pharmacol. 1994 Nov;129(1):155-62. PubMed PMID: 7974489. 6: Sadło S. Changes of bromopropylate and carbendazim residues during processing of apples into apple puree. Rocz Panstw Zakl Hig. 1996;47(3):273-6. PubMed PMID: 9008401. 7: Corta E, Bakkali A, Barranco A, Berrueta LA, Gallo B, Vicente F, Bogdanov S. Study of the degradation products of bromopropylate, chlordimeform, coumaphos, cymiazole, flumethrin and tau-fluvalinate in aqueous media. Talanta. 2000 Jun 21;52(2):169-80. PubMed PMID: 18967974. 8: Formica G. Gas chromatographic determination of residues of bromopropylate and two of its degradation products in honey. J Assoc Off Anal Chem. 1984 Sep-Oct;67(5):896-901. PubMed PMID: 6501151. 9: van Rillaer W, Beernaert H. Determination of residual bromopropylate and coumaphos in honey and honeycomb by capillary gas chromatography. Z Lebensm Unters Forsch. 1989 Feb;188(2):135-7. PubMed PMID: 2718634. 10: Knowles CO, Ahmad S. Comparative metabolism of chlorobenzilate, chloropropylate, and bromopropylate acaricides by rat hepatic enzymes. Can J Physiol Pharmacol. 1971 Jun;49(6):590-7. PubMed PMID: 5088463. 11: Jiménez JJ, Bernal JL, del Nozal MJ, Toribio L, Bernal J. Determination of impurities in pesticides and their degradation products formed during the wine-making process by solid-phase extraction and gas chromatography with detection by electron ionization mass spectrometry. II. Bromopropylate, trichlorphon, parathion-methyl and tebuconazole. Rapid Commun Mass Spectrom. 2004;18(22):2629-36. PubMed PMID: 15481093. 12: Liapis KS, Aplada-Sarlis P, Kyriakidis NV. Rapid multi-residue method for the determination of azinphos methyl, bromopropylate, chlorpyrifos, dimethoate, parathion methyl and phosalone in apricots and peaches by using negative chemical ionization ion trap technology. J Chromatogr A. 2003 May 9;996(1-2):181-7. PubMed PMID: 12830919. 13: Argarate N, Arestin M, Ramón-Azcón J, Alfaro B, Barranco A, Sánchez-Baeza F, Marco MP. Evaluation of immunoassays as an alternative for the rapid determination of pesticides in wine and grape samples. J AOAC Int. 2010 Jan-Feb;93(1):2-11. PubMed PMID: 20334160. 14: Jacobsen H, Østergaard G, Lam HR, Poulsen ME, Frandsen H, Ladefoged O, Meyer O. Repeated dose 28-day oral toxicity study in Wistar rats with a mixture of five pesticides often found as residues in food: alphacypermethrin, bromopropylate, carbendazim, chlorpyrifos and mancozeb. Food Chem Toxicol. 2004 Aug;42(8):1269-77. PubMed PMID: 15207377. 15: Ramón-Azcón J, Yasukawa T, Mizutani F. Sensitive and spatially multiplexed detection system based on dielectrophoretic manipulation of DNA-encoded particles used as immunoreactions platform. Anal Chem. 2011 Feb 1;83(3):1053-60. doi: 10.1021/ac102854z. Epub 2010 Dec 30. PubMed PMID: 21192674. 16: Tuzimski T, Rejczak T. Determination of pesticides in sunflower seeds by high-performance liquid chromatography coupled with a diode array detector. J AOAC Int. 2014 Jul-Aug;97(4):1012-20. PubMed PMID: 25145131. 17: Pelit L, Dizdaş TN. Preparation and application of a polythiophene solid-phase microextraction fiber for the determination of endocrine-disruptor pesticides in well waters. J Sep Sci. 2013 Oct;36(19):3234-41. doi: 10.1002/jssc.201300633. Epub 2013 Aug 29. PubMed PMID: 23913719. 18: Tsiropoulos NG, Amvrazi EG. Determination of pesticide residues in honey by single-drop microextraction and gas chromatography. J AOAC Int. 2011 Mar-Apr;94(2):634-44. PubMed PMID: 21563700. 19: Adamczyk S, Lázaro R, Pérez-Arquillué C, Bayarri S, Herrera A. Impact of the use of fluvalinate on different types of beeswax from Spanish hives. Arch Environ Contam Toxicol. 2010 Apr;58(3):733-9. doi: 10.1007/s00244-009-9387-7. Epub 2009 Sep 16. PubMed PMID: 19756841. 20: Amendola G, Pelosi P, Dommarco R. Solid-phase extraction for multi-residue analysis of pesticides in honey. J Environ Sci Health B. 2011;46(1):24-34. doi: 10.1080/03601234.2010.515170. PubMed PMID: 20936565.