Azimsulfuron | CAS# 120162-55-2 | Herbicide

MedKoo Cat#: 571209 | Name: Azimsulfuron

Description:

WARNING: This product is for research use only, not for human or veterinary use.

Azimsulfuron is a sulfonylurea herbicide useful in controlling weeds in paddy fields.

Chemical Structure

Azimsulfuron

CAS#120162-55-2

Theoretical Analysis

MedKoo Cat#: 571209

Name: Azimsulfuron

CAS#: 120162-55-2

Chemical Formula: C13H16N10O5S

Exact Mass: 424.1026

Molecular Weight: 424.40

Elemental Analysis: C, 36.79; H, 3.80; N, 33.00; O, 18.85; S, 7.55

Price and Availability

This product is currently not in stock but may be available through custom synthesis. To ensure cost efficiency, the minimum order quantity is 1 gram. The estimated lead time is 2 to 4 months, with pricing dependent on the complexity of the synthesis (typically high for intricate chemistries). Quotes for quantities below 1 gram will not be provided. To request a quote, please click the button below. Note: If this product becomes available in stock in the future, pricing will be listed accordingly.

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Related CAS #

No Data

Synonym

Azimsulfuron; A 8947; A-8947; A8947

IUPAC/Chemical Name

N-((4,6-dimethoxypyrimidin-2-yl)carbamoyl)-1-methyl-4-(2-methyl-2H-tetrazol-5-yl)-1H-pyrazole-5-sulfonamide

InChi Key

MAHPNPYYQAIOJN-UHFFFAOYSA-N

InChi Code

InChI=1S/C13H16N10O5S/c1-22-11(7(6-14-22)10-18-21-23(2)19-10)29(25,26)20-13(24)17-12-15-8(27-3)5-9(16-12)28-4/h5-6H,1-4H3,(H2,15,16,17,20,24)

SMILES Code

O=S(C1=C(C2=NN(C)N=N2)C=NN1C)(NC(NC3=NC(OC)=CC(OC)=N3)=O)=O

Appearance

Solid powder

Purity

>98% (or refer to the Certificate of Analysis)

Shipping Condition

Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition

Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).

Solubility

Soluble in DMSO

Shelf Life

>2 years if stored properly

Drug Formulation

This drug may be formulated in DMSO

Stock Solution Storage

0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code

2934.99.9001

More Info

Instruction

View handling instruction

Preparing Stock Solutions

The following data is based on the product molecular weight 424.40 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Concentration / Solvent Volume / Mass	1 mg	5 mg	10 mg
1 mM	1.15 mL	5.76 mL	11.51 mL
5 mM	0.23 mL	1.15 mL	2.3 mL
10 mM	0.12 mL	0.58 mL	1.15 mL
50 mM	0.02 mL	0.12 mL	0.23 mL

1: Valle A, Boschin G, Negri M, Abbruscato P, Sorlini C, D'Agostina A, Zanardini E. The microbial degradation of azimsulfuron and its effect on the soil bacterial community. J Appl Microbiol. 2006 Aug;101(2):443-52. PubMed PMID: 16882153. 2: García-Jaramillo M, Cox L, Hermosín MC, Cerli C, Kalbitz K. Influence of green waste compost on azimsulfuron dissipation and soil functions under oxic and anoxic conditions. Sci Total Environ. 2016 Apr 15;550:760-7. doi: 10.1016/j.scitotenv.2016.01.142. Epub 2016 Feb 2. PubMed PMID: 26849340. 3: Kwon E, Kim J, Park H, Kim TH. A second triclinic polymorph of azimsulfuron. Acta Crystallogr E Crystallogr Commun. 2016 Sep 23;72(Pt 10):1468-1470. eCollection 2016 Oct 1. PubMed PMID: 27746943; PubMed Central PMCID: PMC5050778. 4: Pusino A, Pinna MV, Gessa C. Azimsulfuron sorption--desorption on soil. J Agric Food Chem. 2004 Jun 2;52(11):3462-6. PubMed PMID: 15161216. 5: Pinna MV, Zema M, Gessa C, Pusino A. Structural elucidation of phototransformation products of azimsulfuron in water. J Agric Food Chem. 2007 Aug 8;55(16):6659-63. Epub 2007 Jul 6. PubMed PMID: 17616138. 6: Jeon Y, Kim J, Kwon E, Kim TH. Crystal structure of azimsulfuron. Acta Crystallogr E Crystallogr Commun. 2015 Jun 13;71(Pt 7):o470-1. doi: 10.1107/S2056989015010968. eCollection 2015 Jul 1. PubMed PMID: 26279913; PubMed Central PMCID: PMC4518981. 7: Singh V, Jat ML, Ganie ZA, Chauhan BS, Gupta RK. Herbicide options for effective weed management in dry direct-seeded rice under scented rice-wheat rotation of western Indo-Gangetic Plains. Crop Prot. 2016 Mar;81:168-176. PubMed PMID: 26941471; PubMed Central PMCID: PMC4767026. 8: Pinna MV, Pusino A, Gessa C. Sorption and degradation of azimsulfuron on iron(III)-rich soil colloids. J Agric Food Chem. 2004 Dec 29;52(26):8081-5. PubMed PMID: 15612799. 9: Santín-Montanyá MI, Jiménez J, Ocaña L, Sánchez FJ. Effects of sprout cutting plus systemic herbicide application on the initial growth of giant reed. J Environ Sci Health B. 2013;48(4):285-90. doi: 10.1080/03601234.2013.743784. PubMed PMID: 23374047. 10: Pelentridou K, Stathatos E, Karasali H, Lianos P. Photodegradation of the herbicide azimsulfuron using nanocrystalline titania films as photocatalyst and low intensity Black Light radiation or simulated solar radiation as excitation source. J Hazard Mater. 2009 Apr 30;163(2-3):756-60. doi: 10.1016/j.jhazmat.2008.07.023. Epub 2008 Jul 12. PubMed PMID: 18703278. 11: Lee YJ, Rahman MM, Abd El-Aty AM, Choi JH, Chung HS, Kim SW, Abdel-Aty AM, Shin HC, Shim JH. Detection of three herbicide, and one metabolite, residues in brown rice and rice straw using various versions of the QuEChERS method and liquid chromatography-tandem mass spectrometry. Food Chem. 2016 Nov 1;210:442-50. doi: 10.1016/j.foodchem.2016.05.005. Epub 2016 May 2. PubMed PMID: 27211669. 12: Boschin G, D'Agostina A, Antonioni C, Locati D, Arnoldi A. Hydrolytic degradation of azimsulfuron, a sulfonylurea herbicide. Chemosphere. 2007 Jul;68(7):1312-7. Epub 2007 Feb 27. PubMed PMID: 17328940. 13: Polati S, Bottaro M, Frascarolo P, Gosetti F, Gianotti V, Gennaro MC. HPLC-UV and HPLC-MSn multiresidue determination of amidosulfuron, azimsulfuron, nicosulfuron, rimsulfuron, thifensulfuron methyl, tribenuron methyl and azoxystrobin in surface waters. Anal Chim Acta. 2006 Oct 10;579(2):146-51. Epub 2006 Jul 22. PubMed PMID: 17723738. 14: Ruiz-Santaella JP, Fisher AJ, De Prado R. Alternative control of two biotypes of Echinochloa phyllopogon susceptible and resistant to fenoxaprop-ethyl. Commun Agric Appl Biol Sci. 2003;68(4 Pt A):403-7. PubMed PMID: 15149136. 15: Nanita SC, Padivitage NL. Ammonium chloride salting out extraction/cleanup for trace-level quantitative analysis in food and biological matrices by flow injection tandem mass spectrometry. 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Screening Method for Nine Sulfonylurea Herbicides in Soil and Water by Liquid Chromatography with Ultraviolet Detection. J Agric Food Chem. 1998 Feb 16;46(2):514-519. PubMed PMID: 10554272. 20: Akiyama Y, Yoshioka N, Tsuji M. Determination of ten sulfonyl urea herbicides in unpolished rice by solid-phase extraction cleanup and LC-diode array detection. Shokuhin Eiseigaku Zasshi. 2002 Apr;43(2):99-103. PubMed PMID: 12092420. ^